Chapter 8: Problem 10
What is meant by a chemical bond? Why do atoms form bonds with each other? Why do some elements exist as molecules in nature instead of as free atoms?
Chapter 8: Problem 10
What is meant by a chemical bond? Why do atoms form bonds with each other? Why do some elements exist as molecules in nature instead of as free atoms?
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Get started for freeOxidation of the cyanide ion produces the stable cyanate ion, \(\mathrm{OCN}^{-}\) . The fulminate ion, \(\mathrm{CNO}^{-}\), on the other hand, is very unstable. Fulminate salts explode when struck; \(\mathrm{Hg}(\mathrm{CNO})_{2}\) is used in blasting caps. Write the Lewis structures and assign formal charges for the cyanate and fulminate ions. Why is the fulminate ion so unstable? (C is the central atom in \(\mathrm{OCN}^{-}\) and \(\mathrm{N}\) is the central atom in \(\mathrm{CNO}^{-}\) )
Compare the electron affinity of fluorine to the ionization energy of sodium. Is the process of an electron being “pulled” from the sodium atom to the fluorine atom exothermic or endothermic? Why is NaF a stable compound? Is the overall formation of NaF endothermic or exothermic? How can this be?
Predict the molecular structure (including bond angles) for each of the following. (See Exercises 115 and 116.) a. \(\mathrm{XeCl}_{2}\) b. \(\mathrm{ICl}_{3}\) c. \(\mathrm{TeF}_{4}\) d. \(\mathrm{PCl}_{5}\)
Write electron configurations for the most stable ion formed by each of the elements Al, Ba, Se, and I (when in stable ionic compounds).
Use the following data to estimate \(\Delta H_{\mathrm{f}}^{\circ}\) for barium bromide. $$\mathrm{Ba}(s)+\mathrm{Br}_{2}(g) \longrightarrow \mathrm{BaBr}_{2}(s)$$ $\begin{array}{ll}{\text { Lattice energy }} & {-1985 \mathrm{kJ} / \mathrm{mol}} \\ {\text { First ionization energy of Ba }} & \quad {503 \mathrm{kJ} / \mathrm{mol}} \\ {\text { Second ionization energy of } \mathrm{Ba}} & \quad {965 \mathrm{kJ} / \mathrm{mol}} \\ {\text { Electron affinity of } \mathrm{Br}} & {-325 \mathrm{kJ} / \mathrm{mol}}\\\\{\text { Bond energy of } \mathrm{Br}_{2}} & \quad {193 \mathrm{kJ} / \mathrm{mol}} \\\ {\text { Enthalpy of sublimation of } \mathrm{Ba}} & \quad {178 \mathrm{kJ} / \mathrm{mol}}\end{array}$
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