Chapter 8: Problem 12
How does a bond between Na and Cl differ from a bond between C and O? What about a bond between N and N?
Chapter 8: Problem 12
How does a bond between Na and Cl differ from a bond between C and O? What about a bond between N and N?
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Get started for freeDraw a Lewis structure for the \(N, N\) -dimethylformamide molecule. The skeletal structure is Various types of evidence lead to the conclusion that there is some double bond character to the C-N bond. Draw one or more resonance structures that support this observation.
Hydrogen has an electronegativity value between boron and carbon and identical to phosphorus. With this in mind, rank the following bonds in order of decreasing polarity: \(\mathrm{P}-\mathrm{H}\) , $\mathrm{O}-\mathrm{H}, \mathrm{N}-\mathrm{H}, \mathrm{F}-\mathrm{H}, \mathrm{C}-\mathrm{H} .$
Nitrous oxide \(\left(\mathrm{N}_{2} \mathrm{O}\right)\) has three possible Lewis structures: $$: \mathrm{N}=\mathrm{N}=\dot{\mathrm{O}}\longleftrightarrow: \mathrm{N} \equiv \mathrm{N}-\ddot{\mathrm{Q}} : \longleftrightarrow : \dot{\mathrm{N}}-\mathrm{N} \equiv \mathrm{O}$$ Given the following bond lengths, $\mathrm{N}-\mathrm{N} \qquad 167 \mathrm{pm} \quad \mathrm{N}=\mathrm{O} \quad 115 \mathrm{pm}$ $\mathrm{N}=\mathrm{N} \qquad 120 \mathrm{pm} \quad \mathrm{N}-\mathrm{O} \quad 147 \mathrm{pm}$ \(\mathrm{N} \equiv \mathrm{N} \quad 110 \mathrm{pm}\) rationalize the observations that the N-N bond length in $\mathrm{N}_{2} \mathrm{O}\( is 112 \)\mathrm{pm}\( and that the \)\mathrm{N}-\mathrm{O}$ bond length is 119 \(\mathrm{pm}\) . Assign formal charges to the resonance structures for \(\mathrm{N}_{2} \mathrm{O}\) . Can you eliminate any of the resonance structures on the basis of formal charges? Is this consistent with observation?
Given the following information: Heat of sublimation of \(\mathrm{Li}(s)=166 \mathrm{kJ} / \mathrm{mol}\) Bond energy of \(\mathrm{HCl}=427 \mathrm{kJ} / \mathrm{mol}\) Ionization energy of \(\mathrm{Li}(g)=520 . \mathrm{kJ} / \mathrm{mol}\) Electron affinity of \(\mathrm{Cl}(g)=-349 \mathrm{kJ} / \mathrm{mol}\) Lattice energy of LiCl(s) \(=-829 \mathrm{kJ} / \mathrm{mol}\) Bond energy of \(\mathrm{H}_{2}=432 \mathrm{kJ} / \mathrm{mol}\) Calculate the net change in energy for the following reaction: $$2 \mathrm{Li}(s)+2 \mathrm{HCl}(g) \longrightarrow 2 \mathrm{LiCl}(s)+\mathrm{H}_{2}(g)$$
Consider the following bond lengths: $$\mathrm{C}-\mathrm{O} \quad 143 \mathrm{pm} \quad \mathrm{C}=\mathrm{O} \quad 123 \mathrm{pm} \quad \mathrm{C} \equiv \mathrm{O} \quad 109 \mathrm{pm}$$ In the \(\mathrm{CO}_{3}^{2-}\) ion, all three \(\mathrm{C}-\mathrm{O}\) bonds have identical bond lengths of 136 \(\mathrm{pm} .\) Why?
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