Chapter 8: Problem 18
Most atoms in nature are found bonded together to form compounds instead of existing as individual atoms. Why is this true?
Chapter 8: Problem 18
Most atoms in nature are found bonded together to form compounds instead of existing as individual atoms. Why is this true?
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Get started for freeUse the formal charge arguments to rationalize why \(\mathrm{BF}_{3}\) would not follow the octet rule.
The standard enthalpies of formation for $\mathrm{S}(g), \mathrm{F}(g), \mathrm{SF}_{4}(g),\( and \)\mathrm{SF}_{6}(g)\( are \)+278.8,+79.0,-775,$ and \(-1209 \mathrm{kJ} / \mathrm{mol}\) respectively. a. Use these data to estimate the energy of an \(\mathrm{S}-\) F bond. b. Compare your calculated value to the value given in Table \(8.5 .\) What conclusions can you draw? c. Why are the \(\Delta H_{f}^{\circ}\) values for \(\mathrm{S}(g)\) and \(\mathrm{F}(g)\) not equal to zero, since sulfur and fluorine are elements?
The following electrostatic potential diagrams represent \(\mathrm{CH}_{4}\) , \(\mathrm{NH}_{3},\) or \(\mathrm{H}_{2} \mathrm{O}\) . Label each and explain your choices.
A polyatomic ion is composed of \(\mathrm{C}, \mathrm{N},\) and an unknown element \(\mathrm{X}\) . The skeletal Lewis structure of this polyatomic ion is \([\mathrm{X}-\mathrm{C}-\mathrm{N}]^{-} .\) The ion \(\mathrm{X}^{2-}\) has an electron configuration of \([\text { Ar }] 4 s^{2} 3 d^{10} 4 p^{6} .\) What is element \(X ?\) Knowing the identity of \(X,\) complete the Lewis structure of the polyatomic ion, including all important resonance structures.
Nitrous oxide \(\left(\mathrm{N}_{2} \mathrm{O}\right)\) has three possible Lewis structures: $$: \mathrm{N}=\mathrm{N}=\dot{\mathrm{O}}\longleftrightarrow: \mathrm{N} \equiv \mathrm{N}-\ddot{\mathrm{Q}} : \longleftrightarrow : \dot{\mathrm{N}}-\mathrm{N} \equiv \mathrm{O}$$ Given the following bond lengths, $\mathrm{N}-\mathrm{N} \qquad 167 \mathrm{pm} \quad \mathrm{N}=\mathrm{O} \quad 115 \mathrm{pm}$ $\mathrm{N}=\mathrm{N} \qquad 120 \mathrm{pm} \quad \mathrm{N}-\mathrm{O} \quad 147 \mathrm{pm}$ \(\mathrm{N} \equiv \mathrm{N} \quad 110 \mathrm{pm}\) rationalize the observations that the N-N bond length in $\mathrm{N}_{2} \mathrm{O}\( is 112 \)\mathrm{pm}\( and that the \)\mathrm{N}-\mathrm{O}$ bond length is 119 \(\mathrm{pm}\) . Assign formal charges to the resonance structures for \(\mathrm{N}_{2} \mathrm{O}\) . Can you eliminate any of the resonance structures on the basis of formal charges? Is this consistent with observation?
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