Chapter 8: Problem 20
Describe the type of bonding that exists in the \(\mathrm{F}_{2}(g)\) molecule. How does this type of bonding differ from that found in the \(\mathrm{HF}(g)\) molecule? How is it similar?
Chapter 8: Problem 20
Describe the type of bonding that exists in the \(\mathrm{F}_{2}(g)\) molecule. How does this type of bonding differ from that found in the \(\mathrm{HF}(g)\) molecule? How is it similar?
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Get started for freeUse the following standard enthalpies of formation to estimate the \(\mathrm{N}-\mathrm{H}\) bond energy in ammonia: $\mathrm{N}(g), 472.7 \mathrm{kJ} / \mathrm{mol} ; \mathrm{H}(g),\( \)216.0 \mathrm{kJ} / \mathrm{mol} ; \mathrm{NH}_{3}(g),-46.1 \mathrm{kJ} / \mathrm{mol}$ . Compare your value to the one in Table \(8.5 .\)
The most common type of exception to the octet rule are compounds or ions with central atoms having more than eight electrons around them. PF_. \(\mathrm{PF}_{5}, \mathrm{SF}_{4}, \mathrm{ClF}_{3}\) and \(\mathrm{Br}_{3}^{-}\) are examples of this type of exception. Draw the Lewis structure for these compounds or ions. Which elements, when they have to, can have more than eight electrons around them? How is this rationalized?
The lattice energies of \(\mathrm{FeCl}_{3}, \mathrm{FeCl}_{2},\) and \(\mathrm{Fe}_{2} \mathrm{O}_{3}\) are (in no particular order) \(-2631,-5359,\) and \(-14,774 \mathrm{kJ} / \mathrm{mol}\) . Match the appropriate formula to each lattice energy. Explain.
Give an example of an ionic compound where both the anion and the cation are isoelectronic with each of the following noble gases. a. \(\mathrm{Ne} \quad\) c. \(\mathrm{Kr}\) b. \(\mathrm{Ar} \quad\) d. \(\mathrm{Xe}\)
Write the Lewis structure for $\mathrm{O}_{2} \mathrm{F}_{2} \quad\left(\mathrm{O}_{2} \mathrm{F}_{2}\right.$ exists as \(\mathrm{F}-\mathrm{O}-\mathrm{O}-\mathrm{F} )\). Assign oxidation states and formal charges to the atoms in O2F2. This compound is a vigorous and potent oxidizing and fluorinating agent. Are oxidation states or formal charges more useful in accounting for these properties of \(\mathrm{O}_{2} \mathrm{F}_{2}\)?
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