Chapter 8: Problem 27
Combustion reactions of fossil fuels provide most of the energy needs of the world. Why are combustion reactions of fossil fuels so exothermic?
Chapter 8: Problem 27
Combustion reactions of fossil fuels provide most of the energy needs of the world. Why are combustion reactions of fossil fuels so exothermic?
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Get started for freeWhen molten sulfur reacts with chlorine gas, a vile-smelling orange liquid forms that has an empirical formula of SCl. The structure of this compound has a formal charge of zero on all elements in the compound. Draw the Lewis structure for the vile-smelling orange liquid.
Think of forming an ionic compound as three steps (this is a simplification, as with all models): (1) removing an electron from the metal; (2) adding an electron to the nonmetal; and (3) allowing the metal cation and nonmetal anion to come together. a. What is the sign of the energy change for each of these three processes? b. In general, what is the sign of the sum of the first two processes? Use examples to support your answer. c. What must be the sign of the sum of the three processes? d. Given your answer to part c, why do ionic bonds occur? e. Given your above explanations, why is NaCl stable but not $\mathrm{Na}_{2} \mathrm{Cl} ? \mathrm{NaCl}_{2} ?$ What about MgO compared to \(\mathrm{MgO}_{2} ? \mathrm{Mg}_{2} \mathrm{O} ?\)
For each of the following groups, place the atoms and/or ions in order of decreasing size. a. \(\mathrm{Cu}, \mathrm{Cu}^{+}, \mathrm{Cu}^{2+}\) b. \(\mathrm{Ni}^{2+}, \mathrm{Pd}^{2+}, \mathrm{Pt}^{2+}\) c. \(\mathrm{O}, \mathrm{O}^{-}, \mathrm{O}^{2-}\) d. \(\mathrm{La}^{3+}, \mathrm{Eu}^{3+}, \mathrm{Gd}^{3+}, \mathrm{Yb}^{3+}\) e. $\mathrm{Te}^{2-}, \mathrm{I}^{-}, \mathrm{Cs}^{+}, \mathrm{Ba}^{2+}, \mathrm{La}^{3+}$
Without using Fig. 8.3, predict the order of increasing electronegativity in each of the following groups of elements. a. \(\mathrm{C}, \mathrm{N}, \mathrm{O} \quad\) c. $\mathrm{Si}, \mathrm{Ge}, \mathrm{Sn}$ b. \(\mathrm{S}, \mathrm{Se}, \mathrm{Cl} \quad\) d. $\mathrm{TI}, \mathrm{S}, \mathrm{Ge}$
In general, the higher the charge on the ions in an ionic compound, the more favorable the lattice energy. Why do some stable ionic compounds have \(+1\) charged ions even though \(+4,+5,\) and \(+6\) charged ions would have a more favorable lattice energy?
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