The following electrostatic potential diagrams represent \(\mathrm{CH}_{4}\) , \(\mathrm{NH}_{3},\) or \(\mathrm{H}_{2} \mathrm{O}\) . Label each and explain your choices.

Short Answer

Expert verified
Based on the molecular geometries and electrostatic potential diagrams, the tetrahedral diagram with equal charge distribution should be labeled as CH4, due to the nonpolar nature of C-H bonds and symmetric distribution of charge in the molecule. The trigonal pyramidal diagram with partial charges should be labeled as NH3, as it has a lone pair of electrons on the nitrogen atom contributing to a partial negative charge, and three hydrogen atoms contributing to partial positive charges. Lastly, the bent or V-shaped diagram with partial charges should be labeled as H2O, with the oxygen atom having a partial negative charge due to two lone pairs of electrons, and two hydrogen atoms having partial positive charges.

Step by step solution

01

Molecular Geometries of CH4, NH3, and H2O

Each molecule has a distinct molecular geometry due to the arrangement of atoms in the molecule and their bond angles. 1. CH4 (Methane): CH4 has a tetrahedral geometry with bond angles of 109.5 degrees. 2. NH3 (Ammonia): NH3 has a trigonal pyramidal geometry with bond angles of 107 degrees. 3. H2O (Water): H2O has a bent or V-shaped geometry with bond angles of 104.5 degrees. Step 2: Examine electrostatic potential diagrams
02

Electrostatic Potential Diagram Analysis

Electrostatic potential diagrams show the distribution of charge in a molecule. Blue areas indicate positive charge (electrophilic regions), and red areas indicate negative charge (nucleophilic regions). With this information, we can analyze and label the given diagrams: 1. The diagram with equal distribution of charge around the central atom, with a tetrahedral arrangement, corresponds to CH4. This is due to the nonpolar nature of C-H bonds and symmetric distribution of charge in the molecule. 2. The diagram with three surrounding atoms and a lone pair on the central atom, having a trigonal pyramidal arrangement, corresponds to NH3. The molecule has a lone pair of electrons on the nitrogen atom which contributes to a partial negative charge, while the three hydrogen atoms contribute to partial positive charges. 3. Finally, the diagram showing two surrounding atoms and two lone pairs on the central atom, with a bent arrangement, corresponds to H2O. The oxygen atom has a partial negative charge due to the two lone pairs of electrons, and the two hydrogen atoms have partial positive charges. Step 3: Label the diagrams
03

Final Labeling

Based on our analysis of the molecular geometries and electrostatic potential diagrams: 1. Label the tetrahedral diagram with equal charge distribution as CH4. 2. Label the trigonal pyramidal diagram with partial charges as NH3. 3. Label the bent or V-shaped diagram with partial charges as H2O. Make sure to mention the geometry and distribution of charges as reasons for the labeled choices.

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