Chapter 8: Problem 49
Write electron configurations for a. the cations \(\mathrm{Mg}^{2+}, \mathrm{K}^{+},\) and \(\mathrm{Al}^{3+}\) . b. the anions \(\mathrm{N}^{3-}, \mathrm{O}^{2-}, \mathrm{F}^{-},\) and \(\mathrm{Te}^{2-}\)
Chapter 8: Problem 49
Write electron configurations for a. the cations \(\mathrm{Mg}^{2+}, \mathrm{K}^{+},\) and \(\mathrm{Al}^{3+}\) . b. the anions \(\mathrm{N}^{3-}, \mathrm{O}^{2-}, \mathrm{F}^{-},\) and \(\mathrm{Te}^{2-}\)
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Get started for freeGive an example of an ionic compound where both the anion and the cation are isoelectronic with each of the following noble gases. a. \(\mathrm{Ne} \quad\) c. \(\mathrm{Kr}\) b. \(\mathrm{Ar} \quad\) d. \(\mathrm{Xe}\)
One type of exception to the octet rule are compounds with central atoms having fewer than eight electrons around them. BeH_ and \(\mathrm{BH}_{3}\) are examples of this type of exception. Draw the Lewis structures for \(\mathrm{BeH}_{2}\) and \(\mathrm{BH}_{3} .\)
Use the following data (in kJ/mol) to estimate \(\Delta H\) for the reaction \(S^{-}(g)+e^{-} \rightarrow S^{2-}(g)\) . Include an estimate of uncertainty. $\begin{aligned} \mathrm{S}(s) \longrightarrow \mathrm{S}(g) & \Delta H=277 \mathrm{kJ} / \mathrm{mol} \\ \mathrm{S}(g)+\mathrm{e}^{-} \longrightarrow \mathrm{S}^{-}(g) & \Delta H=-200 \mathrm{kJ} / \mathrm{mol} \end{aligned}$ Assume that all values are known to \(\pm 1 \mathrm{kJ} / \mathrm{mol}\)
Use the following data to estimate \(\Delta H_{\mathrm{f}}^{\circ}\) for barium bromide. $$\mathrm{Ba}(s)+\mathrm{Br}_{2}(g) \longrightarrow \mathrm{BaBr}_{2}(s)$$ $\begin{array}{ll}{\text { Lattice energy }} & {-1985 \mathrm{kJ} / \mathrm{mol}} \\ {\text { First ionization energy of Ba }} & \quad {503 \mathrm{kJ} / \mathrm{mol}} \\ {\text { Second ionization energy of } \mathrm{Ba}} & \quad {965 \mathrm{kJ} / \mathrm{mol}} \\ {\text { Electron affinity of } \mathrm{Br}} & {-325 \mathrm{kJ} / \mathrm{mol}}\\\\{\text { Bond energy of } \mathrm{Br}_{2}} & \quad {193 \mathrm{kJ} / \mathrm{mol}} \\\ {\text { Enthalpy of sublimation of } \mathrm{Ba}} & \quad {178 \mathrm{kJ} / \mathrm{mol}}\end{array}$
Predict the molecular structure, bond angles, and polarity (has a net dipole moment or has no net dipole moment) for each of the following compounds. a. \(\mathrm{SeCl}_{4} \quad\) d. \(\mathrm{CBr}_{4}\) b. \(\mathrm{SO}_{2} \quad\) e. \(\mathrm{IF}_{3}\) c. \(\mathrm{KrF}_{4} \quad\) f. \(\mathrm{ClF}_{5}\)
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