Chapter 10: Problem 48
Explain the significance of bond order. Can bond order be used for quantitative comparisons of the strengths of chemical bonds?
Chapter 10: Problem 48
Explain the significance of bond order. Can bond order be used for quantitative comparisons of the strengths of chemical bonds?
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Get started for freeBased on what you have learned from this chapter and Chapter \(9,\) name a diatomic molecule that has the strongest known chemical bond and one with the weakest known chemical bond.
Describe the change in hybridization (if any) of the Al atom in the following reaction: $$ \mathrm{AlCl}_{3}+\mathrm{Cl}^{-} \longrightarrow \mathrm{AlCl}_{4}^{-} $$
Which of the following ions possess a dipole moment: (a) \(\mathrm{ClF}_{2}^{+},\) (b) \(\mathrm{ClF}_{2}^{-},\) (c) \(\mathrm{IF}_{4}^{+},\) (d) \(\mathrm{IF}_{4}^{-} ?\)
Carbon monoxide (CO) is a poisonous compound due to its ability to bind strongly to \(\mathrm{Fe}^{2+}\) in the hemoglobin molecule. The molecular orbitals of CO have the same energy order as those of the \(\mathrm{N}_{2} \mathrm{~mol}-\) ecule. (a) Draw a Lewis structure of \(\mathrm{CO}\) and assign formal charges. Explain why CO has a rather small dipole moment of 0.12 D. (b) Compare the bond order of CO with that from molecular orbital theory. (c) Which of the atoms (C or O) is more likely to form bonds with the \(\mathrm{Fe}^{2+}\) ion in hemoglobin?
Predict the geometry of the following molecules using the VSEPR method: (a) \(\mathrm{HgBr}_{2}\), (b) \(\mathrm{N}_{2} \mathrm{O}(\mathrm{ar}-\) rangement of atoms is \(\mathrm{NNO}\) ), (c) \(\mathrm{SCN}^{-}\) (arrangement of atoms is \(\mathrm{SCN}\) ).
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