Chapter 11: Problem 24
Use water and mercury as examples to explain adhesion and cohesion.
Short Answer
Expert verified
Adhesion refers to the attraction between different substances, like water in a glass, while cohesion refers to attraction between similar molecules, like water droplets. Specifically, adhesion in water demonstrates through capillary action and mercury adhering to clean glass while cohesion in water shows in the formed 'skin'-like surface and mercury forming large droplets or beads.
Step by step solution
01
Understanding Adhesion
Adhesion is the phenomenon of attraction between molecules of different substances. For instance, when water is poured into a glass, adhesion occurs between the water molecules and the glass molecules, causing the water to 'stick' to the side of the glass.
02
Understanding Cohesion
Cohesion is the phenomenon of attraction between similar molecules. It's exhibited when water forms droplets or when mercury forms beads in a room-temperature environment. The cohesive forces pull the molecules together, leading to a spherical shape.
03
Adhesion Example: Water
Adhesion in water can be demonstrated by the capillary action. When a thin tube is placed in a container of water, the water rises in the tube against the force of gravity. This is due to the adhesive forces between the water and the glass.
04
Cohesion Example: Water
Cohesion in water can be demonstrated by the surface tension. On the water surface, the water molecules are pulled equally in all directions by other molecules except upward, creating a 'skin'-like surface that small creatures can even walk on.
05
Adhesion Example: Mercury
Mercury doesn't adhere to many materials due to its higher surface tension. However, it strongly adheres with materials like glass if the glass is clean and well-prepared, forming a concave meniscus.
06
Cohesion Example: Mercury
Cohesion in mercury is observed when it forms large droplets or beads. Despite the force of gravity, the strong cohesive forces among mercury atoms keep them together. That's why mercury does not wet surfaces and tends to form beads instead of spreading out.
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Capillary Action
Capillary action is an enchanting phenomenon where a liquid can flow in narrow spaces against the force of gravity. It's like watching water magically climb upwards through a thin straw. Have you ever placed a stalk of celery in a glass of colored water and observed how the water creeps up the stalk? That's capillary action in action!
This process is the result of the interplay between cohesive forces, which are the attractions between identical molecules, and adhesive forces, when different materials form a bond. In the instance of water in a narrow tube, adhesive forces between the water molecules and the tube's edges are stronger than the cohesive forces within the water. This imbalance causes water to rise and defy gravity, and the thinner the tube, the higher the water climbs.
To make this concept easier to grasp, imagine a group of people (water molecules) standing in a line holding hands (cohesive forces). If these people start to hold onto a wall (the tube) with their other hand (adhesive forces), those nearest the wall might get pulled in closer, while those further away remain in place, illustrating a rise similar to capillary action.
This process is the result of the interplay between cohesive forces, which are the attractions between identical molecules, and adhesive forces, when different materials form a bond. In the instance of water in a narrow tube, adhesive forces between the water molecules and the tube's edges are stronger than the cohesive forces within the water. This imbalance causes water to rise and defy gravity, and the thinner the tube, the higher the water climbs.
To make this concept easier to grasp, imagine a group of people (water molecules) standing in a line holding hands (cohesive forces). If these people start to hold onto a wall (the tube) with their other hand (adhesive forces), those nearest the wall might get pulled in closer, while those further away remain in place, illustrating a rise similar to capillary action.
Surface Tension
Surface tension is like an invisible elastic sheet stretched across the surface of a liquid, caused by the cohesive forces among the liquid molecules. Picture a water strider skimming across a pond without sinking in – that's the work of surface tension. It occurs because the molecules at the surface of the liquid are not surrounded by similar molecules on all sides, which results in an increased attraction between them, making the surface layer difficult to break.
In technical terms, surface tension is measured as a force per unit length. Think of it as a measure of how tightly molecules at the surface are pulling on each other. You can see surface tension at play when small objects, such as a paperclip, are carefully placed on the water's surface and float despite being denser than water. Those water molecules are working hard, holding hands tightly to create a 'skin' strong enough to support the object. Remember, this 'skin' isn't really solid—it's just the result of the collective strength of those tiny, invisible bonds pulling together.
In technical terms, surface tension is measured as a force per unit length. Think of it as a measure of how tightly molecules at the surface are pulling on each other. You can see surface tension at play when small objects, such as a paperclip, are carefully placed on the water's surface and float despite being denser than water. Those water molecules are working hard, holding hands tightly to create a 'skin' strong enough to support the object. Remember, this 'skin' isn't really solid—it's just the result of the collective strength of those tiny, invisible bonds pulling together.
Molecular Attraction
Molecular attraction is the secret force behind so many of the actions we see liquids perform. It's the 'glue' that holds molecules together and is pivotal in both cohesive and adhesive phenomena. Each molecule has a certain 'social network' – areas where they are attracted to one another. When molecules of the same type meet, we get cohesion, a molecular bond that's like a close-knit family. This leads to the formation of droplets or how liquids can resist tension and pressure.
On the flipside, when different types of molecules fancy each other, they adhere, which is the backbone of adhesion. This is crucial for making the water stick to the inside of the tube in capillary action, or how paint adheres to walls. Interestingly, these forces aren't universal; each substance interacts differently. For example, water molecules are social butterflies, sticking to many surfaces due to their polarity, while non-polar molecules like oil are the loners, sticking mostly to themselves.
On the flipside, when different types of molecules fancy each other, they adhere, which is the backbone of adhesion. This is crucial for making the water stick to the inside of the tube in capillary action, or how paint adheres to walls. Interestingly, these forces aren't universal; each substance interacts differently. For example, water molecules are social butterflies, sticking to many surfaces due to their polarity, while non-polar molecules like oil are the loners, sticking mostly to themselves.