Chapter 12: Problem 35
A beaker of water is initially saturated with dissolved air. Explain what happens when He gas at 1 atm is bubbled through the solution for a long time.
Chapter 12: Problem 35
A beaker of water is initially saturated with dissolved air. Explain what happens when He gas at 1 atm is bubbled through the solution for a long time.
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Get started for freeDescribe how you would use freezing-point depression and osmotic pressure measurements to determine the molar mass of a compound. Why are boiling-point elevation and vapor-pressure lowering normally not used for this purpose?
Iodine \(\left(\mathrm{I}_{2}\right)\) is only sparingly soluble in water (left photo). Yet upon the addition of iodide ions (for example, from KI), iodine is converted to the triiodide ion, which readily dissolves (right photo): $$\mathrm{I}_{2}(s)+\mathrm{I}^{-}(a q) \rightleftharpoons \mathrm{I}_{3}^{-}(a q) $$ Describe the change in solubility of \(\mathrm{I}_{2}\) in terms of the change in intermolecular forces.
The vapor pressure of ethanol \(\left(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{OH}\right)\) at \(20^{\circ} \mathrm{C}\) is \(44 \mathrm{mmHg},\) and the vapor pressure of methanol \(\left(\mathrm{CH}_{3} \mathrm{OH}\right)\) at the same temperature is \(94 \mathrm{mmHg} . \mathrm{A}\) mixture of \(30.0 \mathrm{~g}\) of methanol and \(45.0 \mathrm{~g}\) of ethanol is prepared (and can be assumed to behave as an ideal solution). (a) Calculate the vapor pressure of methanol and ethanol above this solution at \(20^{\circ} \mathrm{C}\). (b) Calculate the mole fraction of methanol and ethanol in the vapor above this solution at \(20^{\circ} \mathrm{C}\). (c) Suggest a method for separating the two components of the solution.
Explain why it is essential that fluids used in intravenous injections have approximately the same osmotic pressure as blood.
Two liquids A and B have vapor pressures of \(76 \mathrm{mmHg}\) and \(132 \mathrm{mmHg},\) respectively, at \(25^{\circ} \mathrm{C}\) What is the total vapor pressure of the ideal solution made up of (a) 1.00 mole of \(\mathrm{A}\) and 1.00 mole of \(\mathrm{B}\), and (b) 2.00 moles of \(\mathrm{A}\) and 5.00 moles of \(\mathrm{B}\) ?
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