Radioactive plutonium-239 \(\left(t_{\frac{1}{2}}=2.44 \times 10^{5} \mathrm{yr}\right)\) is used in nuclear reactors and atomic bombs. If there are \(5.0 \times 10^{2} \mathrm{~g}\) of the isotope in a small atomic bomb, how long will it take for the substance to decay to \(1.0 \times 10^{2} \mathrm{~g},\) too small an amount for an effective bomb?

Short Answer

Expert verified
Therefore, the required time for the decay to \( 1.0 * 10^{2} \, \mathrm{g} \) will be \( [\ln(0.2) / \ln(1/2)] * (2.44 * 10^{5}) \) years.

Step by step solution

01

Understand the radioactive decay

A radioactive substance decays exponentially with time, which means the remaining (undecayed) amount of the substance can be calculated using an exponential decay formula of the form: \( N = N_0 * (1/2)^{t/T}\), where: \( N_0 \) is the initial quantity of the substance, \( N \) is the quantity of the substance at time \( t \), \( T \) is the half-life of the substance.
02

Apply the Radioactive Decay Law

Now, let's apply this formula to our case. We have: \( N_0 = 5.0 * 10^{2} \, \mathrm{g}\), \( N = 1.0 * 10^{2} \, \mathrm{g}\), and \( T = 2.44 * 10^{5} \, \mathrm{yr}\). If we plug these values into the decay formula: \( 1.0 * 10^{2} = 5.0 * 10^{2} * (1/2)^{t/(2.44 * 10^{5})} \)
03

Solve for Time

Solving this equation for time \( t \) will give us the desired answer. First, divide both sides by \( 5.0 * 10^{2} \) to obtain: \( (1/2)^{t/(2.44 * 10^{5})} = 0.2 \). Take the natural logarithm of both sides to solve for \( t \): \[ t = [\ln(0.2) / \ln(1/2)] * (2.44 * 10^{5}).\]

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Radioactive Decay Law
Understanding the radioactive decay law is essential for calculating how substances like plutonium-239 diminish over time. According to this fundamental principle, the decay of radioactive isotopes follows a predictable pattern. Imagine having a stack of playing cards, and with each passing interval, you're required to throw away half of them. The rate at which your pile shrinks represents the exponential decrease characteristic of this law.

For a mathematical understanding, the decay law can be written as:
\begin{align*}N = N_0 \times \bigg(\frac{1}{2}\bigg)^{\frac{t}{T}}\tag{1}\text{or}\tag{2}\text{In more general terms:}N = N_0 \times e^{-\frac{t}{\tau}}\tag{3}\text{Where:} \begin{itemize} \item \(N_0\) is the initial quantity of the substance \item \(N\) is the quantity after time \(t\) \item \(T\) is the half-life of the substance (time it takes for half of it to decay) \item \(e\) is the base of the natural logarithm \item \(\tau\) is the mean lifetime of the substance \end{itemize}
Half-Life
The concept of half-life (denoted as \(T\)) is a key term when dealing with radioactive substances, such as plutonium-239 in our example. It is the time required for half of any quantity of a radioactive isotope to decay. It's a constant, specific to each isotope, and doesn't depend on how much of the isotope you have to start with. Whether you're starting with 5 grams or 500 grams, the half-life remains the same.

Therefore, if you know the half-life of an isotope, you can predict how much time will pass before it reduces to any given fraction of its initial amount. For example, considering plutonium-239's half-life of \(2.44 \times 10^5\) years, one can infer how many years it would take for a specific mass to fall below a threshold critical for certain applications, such as in atomic bombs.
Exponential Decay
Exponential decay refers to the process by which an amount decreases at a rate proportional to its current value. In the context of radioactive decay, this means that the substance decays faster when there is more of it and slower as it becomes less. This process is beautifully consistent and allows us to create models predicting the behavior of a decaying substance over time, like the exponential decay model shown in the radioactive decay law.

The steps to solving our plutonium-239 problem hinge on understanding this model of decay. We see that the initial quantity is depleted not linearly but exponentially, akin to how a glowing ember fades more slowly as it shrinks. This fundamental understanding allows us to navigate complex problems in nuclear chemistry with precision.
Nuclear Chemistry
Nuclear chemistry is the field that deals with the reactions and properties of atomic nuclei. It covers phenomena such as fission, fusion, and, of course, radioactive decay. The isotopes of elements, such as plutonium-239 used in our example, possess nuclear instability, leading them to emit radiation and transform into more stable forms over time.

Understanding the principles of nuclear chemistry, including the calculations of half-life and decay, is not just academic but has real-world implications in fields like medicine, energy production, and national security. As demonstrated in the exercise, knowing how long it takes for a certain mass of a radioactive substance to decay can be a matter of practical significance, such as determining the viability of a plutonium-based bomb or the safety protocols for radioactive waste disposal.

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Most popular questions from this chapter

A certain reaction is known to proceed slowly at room temperature. Is it possible to make the reaction proceed at a faster rate without changing the temperature?

Suggest experimental means by which the rates of the following reactions could be followed: (a) \(\mathrm{CaCO}_{3}(s) \longrightarrow \mathrm{CaO}(s)+\mathrm{CO}_{2}(g)\) (b) \(\mathrm{Cl}_{2}(g)+2 \mathrm{Br}^{-}(a q) \longrightarrow \mathrm{Br}_{2}(a q)+2 \mathrm{Cl}^{-}(a q)\) (c) \(\mathrm{C}_{2} \mathrm{H}_{6}(g) \longrightarrow \mathrm{C}_{2} \mathrm{H}_{4}(g)+\mathrm{H}_{2}(g)\) (d) \(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{I}(g)+\mathrm{H}_{2} \mathrm{O}(l) \longrightarrow\) $$ \mathrm{C}_{2} \mathrm{H}_{5} \mathrm{OH}(a q)+\mathrm{H}^{+}(a q)+\mathrm{I}^{-}(a q) $$

Determine the overall orders of the reactions to which the following rate laws apply: (a) rate \(=k\left[\mathrm{NO}_{2}\right]^{2}\), (b) rate \(=k,(\mathrm{c})\) rate \(=k\left[\mathrm{H}_{2}\right]\left[\mathrm{Br}_{2}\right]^{\frac{1}{2}}\) (d) rate \(=\) \(k[\mathrm{NO}]^{2}\left[\mathrm{O}_{2}\right]\)

The rate constant of a first-order reaction is \(4.60 \times\) \(10^{-4} \mathrm{~s}^{-1}\) at \(350^{\circ} \mathrm{C} .\) If the activation energy is \(104 \mathrm{~kJ} /\) mol, calculate the temperature at which its rate constant is \(8.80 \times 10^{-4} \mathrm{~s}^{-1}\)

The decomposition of dinitrogen pentoxide has been studied in carbon tetrachloride solvent \(\left(\mathrm{CCl}_{4}\right)\) at a certain temperature: $$ 2 \mathrm{~N}_{2} \mathrm{O}_{5} \longrightarrow 4 \mathrm{NO}_{2}+\mathrm{O}_{2} $$ $$ \begin{array}{cc} \hline\left[\mathrm{N}_{2} \mathrm{O}_{5}\right] & \text { Initial Rate }(M / \mathrm{s}) \\ \hline 0.92 & 0.95 \times 10^{-5} \\ 1.23 & 1.20 \times 10^{-5} \\ 1.79 & 1.93 \times 10^{-5} \\ 2.00 & 2.10 \times 10^{-5} \\ 2.21 & 2.26 \times 10^{-5} \\ \hline \end{array} $$ Determine graphically the rate law for the reaction and calculate the rate constant.

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