Chapter 14: Problem 4
Briefly describe the importance of equilibrium in the study of chemical reactions.
Short Answer
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Chapter 14: Problem 4
Briefly describe the importance of equilibrium in the study of chemical reactions.
These are the key concepts you need to understand to accurately answer the question.
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Get started for freeThe equilibrium constant \(\left(K_{\mathrm{c}}\right)\) for the reaction $$2 \mathrm{HCl}(g) \rightleftharpoons \mathrm{H}_{2}(g)+\mathrm{Cl}_{2}(g)$$ is \(4.17 \times 10^{-34}\) at \(25^{\circ} \mathrm{C} .\) What is the equilibrium constant for the reaction $$\mathrm{H}_{2}(g)+\mathrm{Cl}_{2}(g) \rightleftharpoons 2 \mathrm{HCl}(g)$$ at the same temperature?
Consider the following reaction at equilibrium: $$\mathrm{A}(g) \rightleftharpoons 2 \mathrm{~B}(g)$$ From the data shown here, calculate the equilibrium constant (both \(K_{P}\) and \(K_{\mathrm{c}}\) ) at each temperature. Is the reaction endothermic or exothermic? $$ \begin{array}{clr} \text { Temperature }\left({ }^{\circ} \mathrm{C}\right) & {[\mathrm{A}](M)} & {[\mathrm{B}](M)} \\ 200 & 0.0125 & 0.843 \\ 300 & 0.171 & 0.764 \\ 400 & 0.250 & 0.724 \end{array} $$
Write the expressions for the equilibrium constants \(K_{P}\) of the following thermal decomposition reactions: (a) \(2 \mathrm{NaHCO}_{3}(s) \rightleftharpoons\) $$\mathrm{Na}_{2} \mathrm{CO}_{3}(s)+\mathrm{CO}_{2}(g)+\mathrm{H}_{2} \mathrm{O}(g)$$ (b) \(2 \mathrm{CaSO}_{4}(s) \rightleftharpoons\) $$2 \mathrm{CaO}(s)+2 \mathrm{SO}_{2}(g)+\mathrm{O}_{2}(g)$$
A quantity of 1.0 mole of \(\mathrm{N}_{2} \mathrm{O}_{4}\) was introduced into an evacuated vessel and allowed to attain equilibrium at a certain temperature $$\mathrm{N}_{2} \mathrm{O}_{4}(g) \rightleftharpoons 2 \mathrm{NO}_{2}(g)$$ The average molar mass of the reacting mixture was \(70.6 \mathrm{~g} / \mathrm{mol} .\) (a) Calculate the mole fractions of the gases. (b) Calculate \(K_{P}\) for the reaction if the total pressure was 1.2 atm. (c) What would be the mole fractions if the pressure were increased to 4.0 atm by reducing the volume at the same temperature?
Consider the equilibrium $$2 \mathrm{NOBr}(g) \rightleftharpoons 2 \mathrm{NO}(g)+\mathrm{Br}_{2}(g)$$ If nitrosyl bromide, \(\mathrm{NOBr},\) is 34 percent dissociated at \(25^{\circ} \mathrm{C}\) and the total pressure is 0.25 atm, calculate \(K_{P}\) and \(K_{\mathrm{c}}\) for the dissociation at this temperature.
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