Chapter 16: Problem 85
Outline the general procedure of qualitative analysis.
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Chapter 16: Problem 85
Outline the general procedure of qualitative analysis.
These are the key concepts you need to understand to accurately answer the question.
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Get started for freeA \(5.00-\mathrm{g}\) quantity of a diprotic acid was dissolved in water and made up to exactly \(250 \mathrm{~mL}\). Calculate the molar mass of the acid if \(25.0 \mathrm{~mL}\) of this solution required \(11.1 \mathrm{~mL}\) of \(1.00 \mathrm{M}\) KOH for neutralization. Assume that both protons of the acid were titrated.
A \(10.0-\mathrm{mL}\) solution of \(0.300 \mathrm{M} \mathrm{NH}_{3}\) is titrated with a \(0.100 M \mathrm{HCl}\) solution. Calculate the \(\mathrm{pH}\) after the following additions of the \(\mathrm{HCl}\) solution: (a) \(0.0 \mathrm{~mL},\) (b) \(10.0 \mathrm{~mL}\) (c) \(20.0 \mathrm{~mL}\) (d) \(30.0 \mathrm{~mL}\) (e) \(40.0 \mathrm{~mL}\)
How much \(\mathrm{NaOH}\) (in moles) must be added to \(1 \mathrm{~L}\) of a buffer solution that is \(1.8 M\) in acetic acid and \(1.2 M\) in sodium acetate to result in a buffer solution of \(\mathrm{pH} 5.22 ?\) Assume volume to remain constant.
A diprotic acid, \(\mathrm{H}_{2} \mathrm{~A},\) has the following ionization constants: \(K_{a_{1}}=1.1 \times 10^{-3}\) and \(K_{\mathrm{a}_{2}}=2.5 \times 10^{-6} . \mathrm{In}\) order to make up a buffer solution of \(\mathrm{pH} 5.80\), which combination would you choose: NaHA/ \(\mathrm{H}_{2} \mathrm{~A}\) or \(\mathrm{Na}_{2} \mathrm{~A} / \mathrm{NaHA} ?\)
Which of the following solutions can act as a buffer. (a) \(\mathrm{KCl} / \mathrm{HCl}\), (b) \(\mathrm{KHSO}_{4} / \mathrm{H}_{2} \mathrm{SO}_{4}\) (c) \(\mathrm{Na}_{2} \mathrm{HPO}_{4} /\) \(\mathrm{NaH}_{2} \mathrm{PO}_{4}\) (d) \(\mathrm{KNO}_{2} / \mathrm{HNO}_{2} ?\)
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