Chapter 17: Problem 34
What is the role of ATP in biological reactions?
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Chapter 17: Problem 34
What is the role of ATP in biological reactions?
These are the key concepts you need to understand to accurately answer the question.
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Get started for freeDerive the equation $$ \Delta G=R T \ln (Q / K) $$ where \(Q\) is the reaction quotient and describe how you would use it to predict the spontaneity of a reaction.
Which of the following thermodynamic functions are associated only with the first law of thermodynamics: \(S, U, G, H ?\)
The equilibrium constant \(K_{P}\) for the reaction $$ \mathrm{CO}(g)+\mathrm{Cl}_{2}(g) \rightleftharpoons \mathrm{COCl}_{2}(g) $$ is \(5.62 \times 10^{35}\) at \(25^{\circ} \mathrm{C} .\) Calculate \(\Delta G_{\mathrm{f}}^{\circ}\) for \(\mathrm{COCl}_{2}\) at \(25^{\circ} \mathrm{C}\)
As an approximation, we can assume that proteins exist either in the native (or physiologically functioning) state and the denatured state: $$ \text { native } \rightleftharpoons \text { denatured } $$ The standard molar enthalpy and entropy of the denaturation of a certain protein are \(512 \mathrm{~kJ} / \mathrm{mol}\) and \(1.60 \mathrm{~kJ} / \mathrm{K} \cdot \mathrm{mol},\) respectively. Comment on the signs and magnitudes of these quantities, and calculate the temperature at which the process favors the denatured state.
Give a detailed example of each of the following, with an explanation: (a) a thermodynamically spontaneous process; (b) a process that would violate the first law of thermodynamics; (c) a process that would violate the second law of thermodynamics; (d) an irreversible process; (e) an equilibrium process.
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