Chapter 18: Problem 38
Discuss the advantages and disadvantages of fuel cells over conventional power plants in producing electricity.
Chapter 18: Problem 38
Discuss the advantages and disadvantages of fuel cells over conventional power plants in producing electricity.
All the tools & learning materials you need for study success - in one app.
Get started for freeA concentration cell ceases to operate when the concentrations of the two cell compartments are equal. At this stage, is it possible to generate an emf from the cell by adjusting another parameter without changing the concentrations? Explain.
For each of the following redox reactions, (i) write the half-reactions, (ii) write a balanced equation for the whole reaction, (iii) determine in which direction the reaction will proceed spontaneously under standard-state conditions: (a) \(\mathrm{H}_{2}(g)+\mathrm{Ni}^{2+}(a q) \longrightarrow \mathrm{H}^{+}(a q)+\mathrm{Ni}(s)\) (b) \(\mathrm{MnO}_{4}^{-}(a q)+\mathrm{Cl}^{-}(a q) \longrightarrow\) \(\quad \mathrm{Mn}^{2+}(a q)+\mathrm{Cl}_{2}(g)\) (in acid solution) \(\begin{array}{ll}\text { (c) } \mathrm{Cr}(s)+\mathrm{Zn}^{2+}(a q) & \longrightarrow \mathrm{Cr}^{3+}(a q)+\mathrm{Zn}(s)\end{array}\)
What is the difference between a galvanic cell (such as a Daniell cell) and an electrolytic cell?
The diagram here shows an electrolytic cell consisting of a Co electrode in a \(2.0 \mathrm{M} \mathrm{Co}\left(\mathrm{NO}_{3}\right)_{2}\) solution and a Mg electrode in a \(2.0 \mathrm{M} \mathrm{Mg}\left(\mathrm{NO}_{3}\right)_{2}\) solution. (a) Label the anode and cathode and show the halfcell reactions. Also label the signs \((+\) or \(-)\) on the battery terminals. (b) What is the minimum voltage to drive the reaction? (c) After the passage of \(10.0 \mathrm{~A}\) for \(2.00 \mathrm{~h}\) the battery is replaced with a voltmeter and the electrolytic cell now becomes a galvanic cell. Calculate \(E_{\text {cell. }}\) Assume volumes to remain constant at \(1.00 \mathrm{~L}\) in each compartment.
The cathode reaction in the Leclanché cell is given by $$2 \mathrm{MnO}_{2}(s)+\mathrm{Zn}^{2+}(a q)+2 e^{-} \longrightarrow \mathrm{ZnMn}_{2} \mathrm{O}_{4}(s)$$ If a Leclanché cell produces a current of \(0.0050 \mathrm{~A}\), calculate how many hours this current supply will last if there are initially \(4.0 \mathrm{~g}\) of \(\mathrm{MnO}_{2}\) present in the cell. Assume that there is an excess of \(\mathrm{Zn}^{2+}\) ions.
What do you think about this solution?
We value your feedback to improve our textbook solutions.