Chapter 19: Problem 51
Describe how you would use a radioactive iodine isotope to demonstrate that the following process is in dynamic equilibrium: $$\mathrm{PbI}_{2}(s) \rightleftharpoons \mathrm{Pb}^{2+}(a q)+2 \mathrm{I}^{-}(a q)$$
Chapter 19: Problem 51
Describe how you would use a radioactive iodine isotope to demonstrate that the following process is in dynamic equilibrium: $$\mathrm{PbI}_{2}(s) \rightleftharpoons \mathrm{Pb}^{2+}(a q)+2 \mathrm{I}^{-}(a q)$$
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Get started for freeTwo radioactive isotopes \(\mathrm{X}\) and \(\mathrm{Y}\) have the same molar amount at \(t=0 .\) A week later, there are four times as many \(\mathrm{X}\) as there are \(\mathrm{Y} .\) If the half-life of \(\mathrm{X}\) is \(2.0 \mathrm{~d}\), calculate the half-life of \(\mathrm{Y}\) in days.
Why do radioactive decay series obey first-order kinetics?
What is the source of heat for volcanic activities on Earth?
Write balanced nuclear equations for the following reactions and identify X: (a) \(\mathrm{X}(\mathrm{p}, \alpha){ }_{6}^{12} \mathrm{C}\) (b) \({ }_{13}^{27} \mathrm{Al}(\mathrm{d}, \alpha) \mathrm{X}\) (c) \(\frac{55}{25} \mathrm{Mn}(\mathrm{n}, \gamma) \mathrm{X}\).
Nuclear waste disposal is one of the major concerns of the nuclear industry. In choosing a safe and stable environment to store nuclear wastes, consideration must be given to the heat released during nuclear decay. As an example, consider the \(\beta\) decay of \({ }^{90} \mathrm{Sr}\) \((89.907738 \mathrm{amu})\) $${ }_{38}^{90} \mathrm{Sr} \longrightarrow{ }_{39}^{90} \mathrm{Y}+{ }_{-1}^{0} \beta \quad t_{\frac{1}{2}}=28.1 \mathrm{yr}$$ The \({ }^{90} \mathrm{Y}\) (89.907152 amu) further decays as follows: $${ }_{39}^{90} \mathrm{Y} \longrightarrow{ }_{40}^{90} \mathrm{Zr}+{ }_{-1}^{0} \beta \quad t_{\frac{1}{2}}=64 \mathrm{~h}$$ Zirconium-90 (89.904703 amu) is a stable isotope. (a) Use the mass defect to calculate the energy released (in joules) in each of the above two decays. (The mass of the electron is \(5.4857 \times 10^{-4}\) amu. \()\) (b) Starting with one mole of \({ }^{90} \mathrm{Sr}\), calculate the number of moles of \({ }^{90} \mathrm{Sr}\) that will decay in a year. (c) Calculate the amount of heat released (in kilojoules) corresponding to the number of moles of \({ }^{90} \mathrm{Sr}\) decayed to \({ }^{90} \mathrm{Zr}\) in \((\mathrm{b})\)
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