Chapter 20: Problem 2
Briefly outline the main processes of the nitrogen and oxygen cycles.
Chapter 20: Problem 2
Briefly outline the main processes of the nitrogen and oxygen cycles.
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Assume that the formation of nitrogen dioxide: $$ 2 \mathrm{NO}(g)+\mathrm{O}_{2}(g) \longrightarrow 2 \mathrm{NO}_{2}(g) $$ is an elementary reaction. (a) Write the rate law for this reaction. (b) A sample of air at a certain temperature is contaminated with \(2.0 \mathrm{ppm}\) of \(\mathrm{NO}\) by volume. Under these conditions, can the rate law be simplified? If so, write the simplified rate law. (c) Under the conditions described in (b), the half-life of the reaction has been estimated to be \(6.4 \times 10^{3} \mathrm{~min} .\) What would the half- life be if the initial concentration of NO were \(10 \mathrm{ppm} ?\)
Calculate the standard enthalpy of formation \(\left(\Delta H_{\mathrm{f}}^{\circ}\right)\) of \(\mathrm{ClO}\) from the following bond enthalpies: \(\mathrm{Cl}_{2}\) : \(242.7 \mathrm{~kJ} / \mathrm{mol} ; \mathrm{O}_{2}: 498.7 \mathrm{~kJ} / \mathrm{mol} ; \mathrm{ClO}: 206 \mathrm{~kJ} / \mathrm{mol} .\)
Describe the properties that make radon an indoor pollutant. Would radon be more hazardous if \({ }^{222} \mathrm{Rn}\) had a longer half-life?
Name the gas that is largely responsible for the acid rain phenomenon.
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