A concentration of \(8.00 \times 10^{2}\) ppm by volume of \(\mathrm{CO}\) is considered lethal to humans. Calculate the minimum mass of CO in grams that would become a lethal concentration in a closed room \(17.6 \mathrm{~m}\) long, \(8.80 \mathrm{~m}\) wide, and \(2.64 \mathrm{~m}\) high. The temperature and pressure are \(20.0^{\circ} \mathrm{C}\) and \(756 \mathrm{mmHg}\), respectively.

Short Answer

Expert verified
The minimum mass of CO that would be lethal in the specified room is 376.5 g.

Step by step solution

01

Calculate Room Volume

To find the volume of the room, multiply the length, width, and height: \(17.6 \, m * 8.8 \, m * 2.64 \, m = 408.678 \, m^{3}\). To convert this to litres (the unit commonly used in gas calculations), remember that 1 m^3 = 1000 L, so the room volume is \(408.678 * 1000 = 408,678 L\).
02

Calculate Moles of Air

To calculate the moles of air in the room, use the ideal gas law rearranged to solve for n: \(n = PV/RT\). Convert temperature to Kelvin: \(T = 20.0^{\circ} \, C + 273.15 = 293.15 \, K\). Convert pressure to atm: \(P = 756 \, mmHg * (1 \, atm / 760 \, mmHg) = 0.995 \, atm\). Substitute the known values to find the moles of air: \(n = (0.995 \, atm) * (408,678 \, L) / (0.0821 \, L \, atm / (mol \, K) * 293.15 \, K) = 1.68 * 10^{7} \, mol\).
03

Calculate Moles of CO

As the lethal concentration of CO is given as 800 ppm, this means that in every 1,000,000 units, 800 units are CO. To find the lethal moles of CO, multiply the total moles of air by the ppm: \(1.68 * 10^{7} \, mol * (800 / 1,000,000) = 13.44 \, mol\) of CO.
04

Calculate Mass of CO

Convert moles of CO to grams using the molar mass of CO. The molar mass of CO = 28.01 g/mol. \(13.44 \, mol * 28.01 \, g/mol = 376.5 \, g\). So the lethal mass of CO for the given room dimensions and conditions is 376.5 g.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

ppm Concentration
Understanding parts per million (ppm) concentration is essential when dealing with dilute substances, such as pollutants in the air or solutes in a solution. PPM is a unit of measurement that describes the number of parts of a substance found within a million parts of a particular medium, typically used when the concentrations are very low.

For instance, a concentration of 800 ppm indicates that for every million parts of air, there are 800 parts of carbon monoxide (CO). When calculating the mass of CO to determine a lethal concentration, we multiply the total volume of air by the ppm value divided by a million to find the volume of CO. This step is crucial because it allows us to link the ppm concentration to the volume measurements we have, which can then be converted into a mass using the molar mass of the substance.
Ideal Gas Law
The ideal gas law, represented by the equation \(PV = nRT\), where \(P\) is the pressure, \(V\) is the volume, \(n\) is the number of moles of gas, \(R\) is the ideal gas constant, and \(T\) is the temperature in Kelvin, is a fundamental equation in chemistry. It relates the physical properties of an ideal gas in a closed system.

In this calculation, we are using the ideal gas law to determine the number of moles of air (\

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