Chapter 22: Problem 30
Magnesium chloride is dissolved in a solution containing sodium bicarbonate. On heating, a white precipitate is formed. Explain what causes the precipitation.
Chapter 22: Problem 30
Magnesium chloride is dissolved in a solution containing sodium bicarbonate. On heating, a white precipitate is formed. Explain what causes the precipitation.
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Solid \(\mathrm{PCl}_{5}\) exists as \(\left[\mathrm{PCl}_{4}^{+}\right]\left[\mathrm{PCl}_{6}^{-}\right] .\) Draw Lewis structures for these ions. Describe the hybridization state of the \(\mathrm{P}\) atoms.
Describe two laboratory and two industrial preparations for hydrogen.
Lubricants used in watches usually consist of longchain hydrocarbons. Oxidation by air forms solid polymers that eventually destroy the effectiveness of the lubricants. It is believed that one of the initial steps in the oxidation is removal of a hydrogen atom (hydrogen abstraction). By replacing the hydrogen atoms at reactive sites with deuterium atoms, it is possible to substantially slow the overall oxidation rate. Why? (Hint: Consider the kinetic isotope effect.)
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