Chapter 23: Problem 2
Why is zinc not considered a transition metal?
Short Answer
Expert verified
Zinc is not considered a transition metal because it has a fully filled d subshell in its ground state and all its excited states, thus lacks the ability to shift d orbital electrons during bonding, a key characteristic of transition metals.
Step by step solution
01
Definition of Transition Metals
Transition metals are elements that have (or can have) an incomplete d subshell. This means they can shift the electrons in the d orbitals to higher or lower energy levels to participate in chemical bonding.
02
Electronic Configuration of Zinc
The electronic configuration of zinc is [Ar] 3d^{10} 4s^{2}. In the ground state, all electronic levels are full, with 2 electrons in the 4s orbital and 10 electrons in the 3d orbital.
03
Analysis of Zinc's Electronic Configuration
Despite having electrons in the d orbital, zinc is not usually considered a transition metal because its d orbital is full in both the ground state and all excited states. This means zinc cannot shift electrons from the d orbital to higher orbitals to participate in chemical bonding, which is the key characteristic of transition metals.
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Incomplete d Subshell
Understanding the concept of the incomplete d subshell is crucial for defining transition metals. Transition metals are characterized by their ability to have an incomplete d subshell, which means their d orbitals do not have the maximum number of electrons, which is 10.
This characteristic enables transition metals to exhibit a wide array of chemical behaviors, particularly in how they form bonds with other elements. By having an incomplete d subshell, they can easily accept or donate electrons during chemical reactions. This flexibility allows transition metals to participate in a rich chemistry, including catalysis and the formation of colorful compounds, often by providing a varying oxidation state.
The concept of an incomplete d subshell underpins many principles of inorganic chemistry, and helps explain the unique properties of transition metals compared to other elements in the periodic table.
This characteristic enables transition metals to exhibit a wide array of chemical behaviors, particularly in how they form bonds with other elements. By having an incomplete d subshell, they can easily accept or donate electrons during chemical reactions. This flexibility allows transition metals to participate in a rich chemistry, including catalysis and the formation of colorful compounds, often by providing a varying oxidation state.
The concept of an incomplete d subshell underpins many principles of inorganic chemistry, and helps explain the unique properties of transition metals compared to other elements in the periodic table.
Electronic Configuration
Electronic configuration refers to the arrangement of electrons in an atom's orbitals, following the principles of quantum mechanics. The electrons are distributed in different layers or shells, and within each shell in subshells (s, p, d, f).
The d subshell is of particular interest when discussing transition metals. In the case of zinc, the electron configuration is typically written as [Ar] 3d^{10} 4s^{2}, indicating a filled d subshell with 10 electrons and a filled s subshell with 2 electrons.
A precise understanding of electronic configuration is vital for studying chemical properties and predicting the behavior of an element in a chemical reaction. The filling of electron orbitals follows a specific order, and the pattern in which they fill provides insight into an element's reactivity, the types of bonds it can form, and its placement within the periodic table.
The d subshell is of particular interest when discussing transition metals. In the case of zinc, the electron configuration is typically written as [Ar] 3d^{10} 4s^{2}, indicating a filled d subshell with 10 electrons and a filled s subshell with 2 electrons.
A precise understanding of electronic configuration is vital for studying chemical properties and predicting the behavior of an element in a chemical reaction. The filling of electron orbitals follows a specific order, and the pattern in which they fill provides insight into an element's reactivity, the types of bonds it can form, and its placement within the periodic table.
Chemical Bonding
Chemical bonding is the process where atoms combine to form molecules and compounds. This happens through the interaction of their outer shell electrons, known as valence electrons. There are several types of strong bonds including ionic, covalent, and metallic bonding, each with distinct characteristics.
Transition metals uniquely influence chemical bonding due to their incomplete d subshells. This allows them to partake in complex bonding scenarios not typically accessible to other elements. For instance, they can form coordination compounds by bonding with several ligands via dative covalent bonds.
Their variable oxidation states, a direct result of their flexible electron configuration in the d subshell, allow these metals to facilitate redox reactions. Understanding the bonding mechanics of transition metals is essential to grasp their role in both biological processes and industrial applications.
Transition metals uniquely influence chemical bonding due to their incomplete d subshells. This allows them to partake in complex bonding scenarios not typically accessible to other elements. For instance, they can form coordination compounds by bonding with several ligands via dative covalent bonds.
Their variable oxidation states, a direct result of their flexible electron configuration in the d subshell, allow these metals to facilitate redox reactions. Understanding the bonding mechanics of transition metals is essential to grasp their role in both biological processes and industrial applications.
Zinc Properties
Zinc is a metal that, at first glance, shares some properties common to the transition metals, such as being a good conductor of electricity. However, zinc has a unique electronic configuration of [Ar] 3d^{10} 4s^{2}, meaning its d subshell is fully occupied, a stark contrast to the defining incomplete d subshell of a true transition metal.
Because its 3d orbital is full, zinc does not exhibit the classic transition metal behavior of forming variable oxidation states; it typically only displays a +2 oxidation state. Furthermore, zinc's inability to alter its electronic d subshell configuration limits its role in chemical bonding compared to other transition metals. This electronic structure decisively shapes its physical and chemical properties, such as having a relatively low melting point and lacking the catalytic properties characteristic of other transition metals.
Because its 3d orbital is full, zinc does not exhibit the classic transition metal behavior of forming variable oxidation states; it typically only displays a +2 oxidation state. Furthermore, zinc's inability to alter its electronic d subshell configuration limits its role in chemical bonding compared to other transition metals. This electronic structure decisively shapes its physical and chemical properties, such as having a relatively low melting point and lacking the catalytic properties characteristic of other transition metals.