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Chapter 23: Problem 39

Define the terms (a) labile complex, (b) inert complex.

Short Answer

Expert verified
A labile complex refers to a complex where the ligands and central atom can interact readily, often in response to external stimuli such as light or heat. An inert complex is a type where there is a slow exchange rate between the ligands and the central atom, making them stable and unresponsive to quick changes in their environment.

Step by step solution

01

Define Labile Complex

A Labile Complex refers to a type of complex in which the ligands and the central atom can readily interact. This is usually in response to external stimuli such as light or heat. These complexes are characterized by their fast exchange rates with surrounding molecules.
02

Define Inert Complex

An Inert Complex, in contrast, refers to a type of complex where there is a slow exchange rate between the ligands and the central atom. This implies that these complexes do not respond quickly to external stimuli and are therefore stable or 'inert'.

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Most popular questions from this chapter

A student has prepared a cobalt complex that has one of the following three structures: \(\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{6}\right]\) \(\mathrm{Cl}_{3},\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{5} \mathrm{Cl}\right] \mathrm{Cl}_{2},\) or \(\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{4} \mathrm{Cl}_{2}\right] \mathrm{Cl} .\) Explain how the student would distinguish between these possibilities by an electrical conductance experiment. At the student's disposal are three strong electrolytes \(-\mathrm{NaCl}, \mathrm{MgCl}_{2},\) and \(\mathrm{FeCl}_{3}-\) which may be used for comparison purposes.

Write the electron configurations of the following ions: \(\mathrm{V}^{5+}, \mathrm{Cr}^{3+}, \mathrm{Mn}^{2+}, \mathrm{Fe}^{3+}, \mathrm{Cu}^{2+}, \mathrm{Sc}^{3+}, \mathrm{Ti}^{4+}\)

Why is zinc not considered a transition metal?

Why do transition metals have more oxidation states than other elements?

The complex ion \(\left[\mathrm{Ni}(\mathrm{CN})_{2} \mathrm{Br}_{2}\right]^{2-}\) has a squareplanar geometry. Draw the structures of the geometric isomers of this complex.
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