Chapter 23: Problem 7
Give the highest oxidation states for scandium to copper.
Chapter 23: Problem 7
Give the highest oxidation states for scandium to copper.
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Get started for freeA student has prepared a cobalt complex that has one of the following three structures: \(\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{6}\right]\) \(\mathrm{Cl}_{3},\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{5} \mathrm{Cl}\right] \mathrm{Cl}_{2},\) or \(\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{4} \mathrm{Cl}_{2}\right] \mathrm{Cl} .\) Explain how the student would distinguish between these possibilities by an electrical conductance experiment. At the student's disposal are three strong electrolytes \(-\mathrm{NaCl}, \mathrm{MgCl}_{2},\) and \(\mathrm{FeCl}_{3}-\) which may be used for comparison purposes.
Draw structures of all the geometric and optical isomers of each of the following cobalt complexes: (a) \(\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{4} \mathrm{Cl}_{2}\right]^{+},(\mathrm{b})\left[\mathrm{Co}(\mathrm{en})_{3}\right]^{3+}\)
Explain the following facts: (a) Copper and iron have several oxidation states, whereas zinc has only one. (b) Copper and iron form colored ions, whereas zinc does not.
Suggest a method that would allow you to distinguish between \(c i s-\mathrm{Pt}\left(\mathrm{NH}_{3}\right)_{2} \mathrm{Cl}_{2}\) and trans\(\mathrm{Pt}\left(\mathrm{NH}_{3}\right)_{2} \mathrm{Cl}_{2}\)
Complete the following statements for the complex ion \(\left[\mathrm{Cr}\left(\mathrm{C}_{2} \mathrm{O}_{4}\right)_{2}\left(\mathrm{H}_{2} \mathrm{O}\right)_{2}\right]^{-}:\) (a) The oxidation number of Cr is _____ (b) The coordination number of Cr is _____ . (c)_____ is a bidentate ligand.
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