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Chapter 24: Problem 4
Give three sources of methane.
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When a mixture of methane and bromine vapor is exposed to light, the following reaction occurs slowly: \(\mathrm{CH}_{4}(g)+\mathrm{Br}_{2}(g) \longrightarrow \mathrm{CH}_{3} \mathrm{Br}(g)+\mathrm{HBr}(g)\) When a mixture of methane and bromine vapor is exposed to light, the following reaction occurs slowly:
Write structures for the following compounds: (a) 1 -bromo- 3 -methylbenzene, (b) 1 -chloro- 2 -propylbenzene, (c) 1,2,4,5 -tetramethylbenzene.
The combustion of \(3.795 \mathrm{mg}\) of liquid \(\mathrm{B},\) which contains only \(\mathrm{C}, \mathrm{H},\) and \(\mathrm{O},\) with excess oxygen gave \(9.708 \mathrm{mg}\) of \(\mathrm{CO}_{2}\) and \(3.969 \mathrm{mg}\) of \(\mathrm{H}_{2} \mathrm{O} .\) In a molar mass determination, \(0.205 \mathrm{~g}\) of \(\mathrm{B}\) vaporized at 1.00 atm and \(200.0^{\circ} \mathrm{C}\) and occupied a volume of \(89.8 \mathrm{~mL}\). Derive the empirical formula, molar mass, and molecular formula of \(\mathrm{B}\) and draw three plausible structures.
Write structural formulas for the following organic compounds: (a) 3 -methylhexane, (b) 1,3,5 -trichlorocyclohexane, (c) 2,3 -dimethylpentane, (d) 2 -bromo4 -phenylpentane, (e) 3,4,5 -trimethyloctane.
Write the structures of three alkenes that yield 2 -methylbutane on hydrogenation.
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