Chapter 3: Problem 36
Describe how the knowledge of the percent composition by mass of an unknown compound can help us identify the compound.
Chapter 3: Problem 36
Describe how the knowledge of the percent composition by mass of an unknown compound can help us identify the compound.
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Get started for freeMonosodium glutamate (MSG), a food-flavor enhancer, has been blamed for "Chinese restaurant syndrome," the symptoms of which are headaches and chest pains. MSG has the following composition by mass: 35.51 percent \(\mathrm{C}, 4.77\) percent \(\mathrm{H}\), 37.85 percent \(\mathrm{O}, 8.29\) percent \(\mathrm{N},\) and 13.60 percent Na. What is its molecular formula if its molar mass is about \(169 \mathrm{~g}\) ?
Titanium(IV) oxide \(\left(\mathrm{TiO}_{2}\right)\) is a white substance produced by the action of sulfuric acid on the mineral ilmenite \(\left(\mathrm{FeTiO}_{3}\right)\) $$\mathrm{FeTiO}_{3}+\mathrm{H}_{2} \mathrm{SO}_{4} \longrightarrow\mathrm{TiO}_{2}+\mathrm{FeSO}_{4}+\mathrm{H}_{2} \mathrm{O}$$Its opaque and nontoxic properties make it suitable as a pigment in plastics and paints. In one process, \(8.00 \times 10^{3} \mathrm{~kg}\) of \(\mathrm{FeTiO}_{3}\) yielded \(3.67 \times 10^{3} \mathrm{~kg}\) of \(\mathrm{TiO}_{2} .\) What is the percent yield of the reaction?
Without doing any detailed calculations, estimate which element has the highest percent composition by mass in each of the following compounds: (a) \(\mathrm{Hg}\left(\mathrm{NO}_{3}\right)_{2}\) (b) \(\mathrm{NF}_{3}\) (c) \(\mathrm{K}_{2} \mathrm{Cr}_{2} \mathrm{O}_{7}\) (d) \(\mathrm{C}_{2952} \mathrm{H}_{4664} \mathrm{~N}_{812} \mathrm{O}_{832} \mathrm{~S}_{8} \mathrm{Fe}_{4}\)
Allicin is the compound responsible for the characteristic smell of garlic. An analysis of the compound gives the following percent composition by mass: C: 44.4 percent, \(\mathrm{H}: 6.21\) percent, \(\mathrm{S}: 39.5\) percent, \(\mathrm{O}:\) 9.86 percent. Calculate its empirical formula. What is its molecular formula given that its molar mass is about \(162 \mathrm{~g}\) ?
The natural abundances of the two stable isotopes of hydrogen (hydrogen and deuterium) are \({ }_{1}^{1} \mathrm{H}\) : 99.985 percent and \({ }_{1}^{2} \mathrm{H}: 0.015\) percent. Assume that water exists as either \(\mathrm{H}_{2} \mathrm{O}\) or \(\mathrm{D}_{2} \mathrm{O} .\) Calculate the number of \(\mathrm{D}_{2} \mathrm{O}\) molecules in exactly \(400 \mathrm{~mL}\) of water. (Density \(=1.00 \mathrm{~g} / \mathrm{mL} .)\)
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