Ammonia and sulfuric acid react to form ammonium sulfate. (a) Write an equation for the reaction. (b) Determine the starting mass (in grams) of each reactant if \(20.3 \mathrm{~g}\) of ammonium sulfate is produced and \(5.89 \mathrm{~g}\) of sulfuric acid remains unreacted.

Short Answer

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a) The equation for the reaction is \(2NH_3 + H_2SO_4 → (NH_4)_2SO_4\). b) Calculate the initial mass of sulfuric acid (\(H_2SO_4\)) first and then use this value to find the initial mass of ammonia (\(NH_3\)).

Step by step solution

01

Writing the Reaction Equation

The reaction equation for ammonia (\(NH_3\)) and sulfuric acid (\(H_2SO_4\)) forming ammonium sulfate (\((NH_4)_2SO_4\)) is \(2NH_3 + H_2SO_4 → (NH_4)_2SO_4\). It is crucial to ensure the equation is balanced, which in this case it is.
02

Calculation of Molar Masses

To manipulate exact amounts of reactants and products, convert the given masses into moles using their respective molar masses. The molar mass of \(NH_3\) is 17.03 g/mol, of \(H_2SO_4\) is 98.08 g/mol, and of \((NH_4)_2SO_4\) is 132.14 g/mol.
03

Calculation of initial Mass of Sulfuric Acid

From the stoichiometry of the reaction, we know that 1 mole of \(H_2SO_4\) yields 1 mole of \((NH_4)_2SO_4\). Therefore the initial moles of \(H_2SO_4\) is the sum of the moles of \((NH_4)_2SO_4\) produced and the moles of \(H_2SO_4\) remained unreacted. That is \( \frac{20.3g}{132.14g/mol} + \frac{5.89g}{98.08g/mol}\) moles. The initial mass of \(H_2SO_4\) is then this mole number times the molar mass of \(H_2SO_4\).
04

Calculation of initial Mass of Ammonia

According to the stoichiometry of the reaction, 2 moles of \(NH_3\) react with 1 mole of \(H_2SO_4\) to form 1 mole of \((NH_4)_2SO_4\). Hence the initial moles of \(NH_3\) is twice the initial moles of \(H_2SO_4\), calculated in step 3. The initial mass of \(NH_3\) is then this mole number times the molar mass of \(NH_3\).

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