Rubidium is used in "atomic clocks" and other precise electronic equipment. The average atomic mass of \({ }_{37}^{85} \mathrm{Rb}(84.912 \mathrm{amu})\) and \({ }_{37}^{87} \mathrm{Rb}(86.909 \mathrm{amu})\) is 85.47 amu. Calculate the natural abundances of the rubidium isotopes.

Understanding the atomic mass calculation is crucial for grasping the composition of elements on a microscopic level. Every element can consist of different isotopes, each having a unique atomic mass. The average atomic mass of an element, like rubidium in the given exercise, is determined by the weighted average of all its naturally occurring isotopes.

To calculate this average, you need to take into account not only the masses of each isotope but also their natural abundances. The formula for the average atomic mass is given by:
\[ \text{Average atomic mass} = (\text{isotopic mass}_1 \times \text{abundance}_1) + (\text{isotopic mass}_2 \times \text{abundance}_2) + \ldots \]
This formula is the basis of the step-by-step solution to find the natural abundances of rubidium isotopes.

Isotopic abundance refers to the percentage of an isotope in a naturally occurring sample of an element. It tells us how much of each isotope of an element you can expect to find and is crucial for calculating the average atomic mass. Different isotopes of an element have nearly identical chemical properties but varying atomic masses.

Because isotopic abundances are percentages, they must always add up to 100%. This fact was used in the exercise to set up the first equation (\( x + y = 100 \)). In the context of the exercise for rubidium, knowing the isotopic abundance allows scientists to precisely calculate atomic masses, which are critical for making 'atomic clocks' and other sensitive devices.

In chemistry, solving systems of equations plays a significant role in quantitatively analyzing substances. When dealing with multiple unknowns, like isotopic abundances, we use systems of equations to solve for each unknown. The exercise presented a system of linear equations with two variables, x and y, which represent the abundances of the two isotopes of rubidium.

The method chosen in the step-by-step solution was substitution, a commonly used technique in algebra. Substitution involves rearranging one equation to express one variable in terms of the other and then using that expression to replace the variable in the second equation. The goal is to reduce the system to a single equation with one unknown, which can then be solved. This approach can be visualized by imagining the simultaneous overlap of both isotopes' contributions to the element’s atomic weight—where they meet provides the solution for each's abundance.