A \(35.2-\mathrm{mL}, 1.66 M \mathrm{KMnO}_{4}\) solution is mixed with \(16.7 \mathrm{~mL}\) of \(0.892 \mathrm{M} \mathrm{KMnO}_{4}\) solution. Calculate the concentration of the final solution.

Short Answer

Expert verified
The final concentration of the \( \mathrm{KMnO}_{4} \) solution when 35.2 mL of a 1.66 M solution is mixed with 16.7 mL of a 0.892 M solution is 1.414 M.

Step by step solution

01

Understanding Terms

Molarity (M) is defined as the moles of solute divided by the volume of the solution in liters. Thus, if the molarity and volume of a solution are known, the moles of the solute can be determined using the equation \( moles = Molarity \times Volume \). In this case, we have two \( \mathrm{KMnO}_{4} \) solutions with known molarities and volumes which we can use to find the total moles of \( \mathrm{KMnO}_{4} \).
02

Calculate the Moles of \( \mathrm{KMnO}_{4} \) in Each Solution

The moles of \( \mathrm{KMnO}_{4} \) in the 35.2-mL, 1.66 M solution and in the 16.7 mL, 0.892 M solution can be found with the formula moles = Molarity × Volume. Remember, Volume should be in liters. \n\nFor the 1.66 M solution, \nmoles of \( \mathrm{KMnO}_{4} \) = 1.66 M × 35.2 mL = 1.66 M × 0.0352 L = 0.058432 moles. \n\nFor the 0.892 M solution, \nmoles of \( \mathrm{KMnO}_{4} \) = 0.892 M × 16.7 mL = 0.892 M × 0.0167 L = 0.0149054 moles.
03

Calculate the Total Moles of \( \mathrm{KMnO}_{4} \)

The total moles of \( \mathrm{KMnO}_{4} \) when the two solutions mix can be found by adding the moles from each solution. Thus, \n Total moles of \( \mathrm{KMnO}_{4} \) = moles in 1.66 M solution + moles in 0.892 M solution = 0.058432 moles + 0.0149054 moles = 0.0733374 moles.
04

Calculate the Total Volume

The total volume of the solution when the two are mixed is simply the sum of the individual volumes. Thus, Total volume = Volume of 1.66 M solution + Volume of 0.892 M solution = 35.2 mL + 16.7 mL = 51.9 mL or 0.0519 L.
05

Calculating the Final Concentration

The final concentration of the \( \mathrm{KMnO}_{4} \) solution can now be determined by the equation Molarity = moles/Vol (in Liters). Thus, \n Final Concentration of \( \mathrm{KMnO}_{4} \) = Total moles / Total volume = 0.0733374 moles / 0.0519 L = 1.414 M

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