Which of the following statements is correct? (a) Heat is produced by the collision of gas molecules against one another. (b) When a gas is heated, the molecules collide with one another more often.

Short Answer

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Statement (b) is correct: 'When a gas is heated, the molecules collide with one another more often.'

Step by step solution

01

Examine Statement (a)

Let's examine statement (a): 'Heat is produced by the collision of gas molecules against one another. This implies that the act of collision directly generates heat. However, according to the kinetic theory of gases, heat is a measure of the average kinetic energy of the gas molecules. While collisions play a vital role in distributing this energy evenly among the gas molecules, they do not generate heat directly. So, statement (a) is incorrect.
02

Examine Statement (b)

Now, examine statement (b): 'When a gas is heated, the molecules collide with one another more often.' According to the kinetic theory of gases, when heat is added to a gas, the kinetic energy of the gas molecules increase, they move faster and as a result, they collide more frequently. Therefore, statement (b) correctly depicts the behavior of gas molecules when the gas is heated.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Gas Molecule Collisions
Understanding the dynamics of gas molecule collisions is essential to grasping the kinetic theory of gases. Imagine a room filled with tiny, invisible balls, all moving in random directions at different speeds. These balls represent the gas molecules in a sample. As they zip around, they inevitably bump into each other and also the walls of their container.

During these collisions, energy can be transferred between molecules, but no new energy is created. The collisions are perfectly elastic, meaning that there is no net loss of kinetic energy. Instead, the energy is redistributed among the molecules, which is crucial for maintaining a uniform temperature throughout the gas. This constant shuffling of energy through collisions is an integral part of how the kinetic theory of gases explains the behavior and properties of gases.

In our everyday experience, this equates to the air around us remaining at a relatively stable temperature, as the energy is spread evenly due to the numerous collisions among countless gas molecules.
Heat and Kinetic Energy
When it comes to understanding heat in the context of gases, we're talking about kinetic energy. According to the kinetic theory, the temperature of a gas is directly proportional to the average kinetic energy of its molecules. In simpler terms, the hotter the gas, the faster its molecules are moving.

It's important to note the distinction between heat and temperature, as they are often confused. Heat refers to the total energy transferred from a hotter object to a cooler one, while temperature measures the intensity of heat, or how hot or cold an object is. So, when a gas absorbs heat, what it's really doing is taking in energy, which increases the speed of its molecules. As the molecules speed up, they hit each other and the container walls with greater force and more frequently, leading to an increase in the gas's temperature. That phenomenon explains why we experience warmth when we stand near a heat source—the molecules in the air are moving faster, hitting our skin more often.
Behavior of Gases When Heated
So, what exactly happens to a gas when it's heated? If you increase the temperature of a gas, you're essentially pumping more kinetic energy into its molecules. This gives the molecules more speed, and as a natural consequence, they start colliding more often and with greater energy.

This increase in collision frequency and energy contributes to several important behaviors observed in gases. For one, it causes the gas to expand. As the molecules move faster and collide more vehemently, they exert more pressure against their container, often resulting in an increase in volume if the container is flexible, like a balloon.

Another consequence is the increase in pressure within a rigid container where the volume can't change. The more energetic collisions against the walls of the container mean higher pressure, which is illustrated by the ideal gas law equation, \( PV = nRT \), where P is the pressure, V is the volume, T is temperature, and n is the amount of gas. This equation neatly ties together the relationship between the physical properties of a gas and shows how changes in temperature can lead to changes in pressure and volume. Thus, when a gas is heated, we not only see an increase in molecular speed and collision frequency, but also changes in its physical properties, depending on the constraints of their environment.

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Most popular questions from this chapter

Estimate the distance (in nanometers) between molecules of water vapor at \(100^{\circ} \mathrm{C}\) and 1.0 atm. Assume ideal behavior. Repeat the calculation for liquid water at \(100^{\circ} \mathrm{C}\), given that the density of water is \(0.96 \mathrm{~g} / \mathrm{cm}^{3}\) at that temperature. Comment on your results. (Assume water molecule to be a sphere with a diameter of \(0.3 \mathrm{nm} .\) ) (Hint: First calculate the number density of water molecules. Next, convert the number density to linear density, that is, number of molecules in one direction.)

A sample of air contains only nitrogen and oxygen gases whose partial pressures are 0.80 atm and 0.20 atm, respectively. Calculate the total pressure and the mole fractions of the gases.

A certain amount of gas at \(25^{\circ} \mathrm{C}\) and at a pressure of 0.800 atm is contained in a glass vessel. Suppose that the vessel can withstand a pressure of 2.00 atm. How high can you raise the temperature of the gas without bursting the vessel?

A stockroom supervisor measured the contents of a partially filled 25.0 -gallon acetone drum on a day when the temperature was \(18.0^{\circ} \mathrm{C}\) and atmospheric pressure was \(750 \mathrm{mmHg}\), and found that 15.4 gallons of the solvent remained. After tightly sealing the drum, an assistant dropped the drum while carrying it upstairs to the organic laboratory. The drum was dented and its internal volume was decreased to 20.4 gallons. What is the total pressure inside the drum after the accident? The vapor pressure of acetone at \(18.0^{\circ} \mathrm{C}\) is \(400 \mathrm{mmHg} .\)

A mixture of \(\mathrm{Na}_{2} \mathrm{CO}_{3}\) and \(\mathrm{MgCO}_{3}\) of mass \(7.63 \mathrm{~g}\) is reacted with an excess of hydrochloric acid. The \(\mathrm{CO}_{2}\) gas generated occupies a volume of \(1.67 \mathrm{~L}\) at 1.24 atm and \(26^{\circ} \mathrm{C}\). From these data, calculate the percent composition by mass of \(\mathrm{Na}_{2} \mathrm{CO}_{3}\) in the mixture.

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