Chapter 7: Problem 13
What are photons? What role did Einstein's explanation of the photoelectric effect play in the development of the particle-wave interpretation of the nature of electromagnetic radiation?
Chapter 7: Problem 13
What are photons? What role did Einstein's explanation of the photoelectric effect play in the development of the particle-wave interpretation of the nature of electromagnetic radiation?
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Get started for freeA laser is used in treating retina detachment. The wavelength of the laser beam is \(514 \mathrm{nm}\) and the power is \(1.6 \mathrm{~W}\). If the laser is turned on for \(0.060 \mathrm{~s}\) during surgery, calculate the number of photons emitted by the laser. \((1 \mathrm{~W}=1 \mathrm{~J} / \mathrm{s})\)
Which of the following species has the most unpaired electrons: \(\mathrm{S}^{+}, \mathrm{S},\) or \(\mathrm{S}^{-} ?\) Explain how you arrive at your answer.
Use the Aufbau principle to obtain the ground-state electron configuration of technetium.
Indicate the total number of (a) \(p\) electrons in \(\mathrm{N}\) \((Z=7),(b) s\) electrons in \(\operatorname{Si}(Z=14),\) and (c) \(3 d\) electrons in \(\mathrm{S}(Z=16)\)
All molecules undergo vibrational motions. Quantum mechanical treatment shows that the vibrational energy, \(E_{\mathrm{vib}},\) of a diatomic molecule like \(\mathrm{HCl}\) is given by $$ E_{\mathrm{vib}}=\left(n+\frac{1}{2}\right) h \nu $$ where \(n\) is a quantum number given by \(n=0,1,2,\) \(3, \ldots\) and \(\nu\) is the fundamental frequency of vibration. (a) Sketch the first three vibrational energy levels for \(\mathrm{HCl}\). (b) Calculate the energy required to excite a HCl molecule from the ground level to the first excited level. The fundamental frequency of vibration for \(\mathrm{HCl}\) is \(8.66 \times 10^{13} \mathrm{~s}^{-1} .\) (c) The fact that the lowest vibrational energy in the ground level is not zero but equal to \(\frac{1}{2} h v\) means that molecules will vibrate at all temperatures, including the absolute zero. Use the Heisenberg uncertainty principle to justify this prediction. (Hint: Consider a nonvibrating molecule and predict the uncertainty in the momentum and hence the uncertainty in the position.)
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