Chapter 7: Problem 27
Is it possible for a fluorescent material to emit radiation in the ultraviolet region after absorbing visible light? Explain your answer.
Short Answer
Expert verified
No, it is not possible for a fluorescent material to emit radiation in the ultraviolet region after absorbing visible light because this process would violate the conservation of energy principle, as ultraviolet light has more energy compared to visible light.
Step by step solution
01
Understanding of Fluorescence
Fluorescence is a type of luminescence where a substance absorbs light at a certain wavelength and re-emits light at a longer wavelength. This happens because photons, being absorbed by the substance, cause their electrons to move to higher energy levels. But shortly after, these electrons fall back to their original energy level, emitting the excess energy as photons.
02
Understanding of Electromagnetic Spectrum
In the electromagnetic spectrum, different types of light are categorized by their different wavelengths. Ultraviolet light has a shorter wavelength relative to visible light. Thus, ultraviolet light possesses more energy compared to that of visible light.
03
Deriving the Conclusion
Since fluorescence involves the emission of light at a longer wavelength (i.e., less energy), a substance cannot absorb light in the visible range (lower energy) and emit light in the ultraviolet range (higher energy). The conservation of energy principle does not allow this shift from a lower energy level to a higher one, thus providing the answer to the given exercise.
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Luminescence
Luminescence is a fascinating phenomenon seen in certain materials that can emit light after they have absorbed energy. It's quite different from incandescence, which is just the emission of light from something hot. There are several types of luminescence, but in the context of our exercise, we focus on fluorescence. Imagine a glow stick when it's cracked, or how certain sea creatures light up in the depths of the ocean - that's luminescence in action, and it doesn't require the material to be heated to emit light.
Within luminescence, fluorescence is the ability of a substance to absorb light at one wavelength - or color - and then emit it at a different, usually longer wavelength. After absorbing energy, the electrons in the fluorescent material get excited to higher energy levels. However, they can't stay there indefinitely and start 'relaxing' by releasing energy as light, in this case, this is radiation distinctly different from what they initially absorbed. Fluorescent materials are used in various applications, from screen displays to research as markers for biological molecules.
Within luminescence, fluorescence is the ability of a substance to absorb light at one wavelength - or color - and then emit it at a different, usually longer wavelength. After absorbing energy, the electrons in the fluorescent material get excited to higher energy levels. However, they can't stay there indefinitely and start 'relaxing' by releasing energy as light, in this case, this is radiation distinctly different from what they initially absorbed. Fluorescent materials are used in various applications, from screen displays to research as markers for biological molecules.
Electromagnetic Spectrum
The electromagnetic spectrum encompasses all types of light, from the very short wavelengths of gamma rays to the long wavelengths of radio waves, with ultraviolet light, visible light, and infrared light residing in between. Visible light is just a small part of this spectrum; it's what can be detected by the human eye.
Each type of electromagnetic radiation within the spectrum is defined by its wavelength (or frequency). Ultraviolet (UV) light has shorter wavelengths and consequently higher energies compared to visible light. In the grand choir of the electromagnetic spectrum, if visible light are the deep basses, ultraviolet light represents the high sopranos in terms of energy. This understanding is crucial for tasks like the one we're discussing where the transfer of energy between different types of light is analyzed.
Each type of electromagnetic radiation within the spectrum is defined by its wavelength (or frequency). Ultraviolet (UV) light has shorter wavelengths and consequently higher energies compared to visible light. In the grand choir of the electromagnetic spectrum, if visible light are the deep basses, ultraviolet light represents the high sopranos in terms of energy. This understanding is crucial for tasks like the one we're discussing where the transfer of energy between different types of light is analyzed.
Conservation of Energy Principle
The conservation of energy principle is a fundamental concept in physics that tells us energy cannot be created or destroyed; it can only be transformed or transferred from one form to another. When applying this to our exercise about fluorescence, consider it like a budget that must be balanced. If a fluorescent material absorbs a certain amount of energy, it can only emit that much energy or less - never more.
This principle ensures the universe's energy bookkeeping remains in check. So, in the case of a fluorescent material absorbing visible light, which is lower in energy, it cannot emit ultraviolet light, which would equate to a higher energy radiation. The substance literally cannot afford to make such a 'payment' because it contradicts the energy conservation rule. Just like in our finances, without extra input, we can't spend more than we have.
This principle ensures the universe's energy bookkeeping remains in check. So, in the case of a fluorescent material absorbing visible light, which is lower in energy, it cannot emit ultraviolet light, which would equate to a higher energy radiation. The substance literally cannot afford to make such a 'payment' because it contradicts the energy conservation rule. Just like in our finances, without extra input, we can't spend more than we have.
Electron Energy Levels
The concept of electron energy levels is linked with the structure of an atom. Electrons orbit the nucleus in specific regions called shells, and each shell corresponds to a certain energy level. When electrons in a material absorb energy, they jump up to higher energy levels, which is like hopping up a staircase. But they can't stay on these upper steps for too long - they quickly 'jump' back down, releasing energy in the form of light.
In fluorescent materials, this jumping-up and cascading down phenomena give rise to the vibrant glows we can observe. It's essential to note that each time an electron falls back to a lower energy level, the emitted light matches the energy 'difference' between the two levels, which is why the light emitted during fluorescence has less energy (and a longer wavelength) than the light absorbed initially.
In fluorescent materials, this jumping-up and cascading down phenomena give rise to the vibrant glows we can observe. It's essential to note that each time an electron falls back to a lower energy level, the emitted light matches the energy 'difference' between the two levels, which is why the light emitted during fluorescence has less energy (and a longer wavelength) than the light absorbed initially.