Recent theoretical calculations suggest that astatine may be a monoatomic
metal rather than a diatomic molecule like the other halogens. (a) Rationalize
this prediction based on astatine's position in the periodic table. (b) The
energy required to remove an electron from one At atom was determined by laser
ionization to be \(9.3175 \mathrm{eV}\). Given that \(1 \mathrm{eV}=1.602\)
\(\times 10^{-19} \mathrm{~J},\) calculate the first ionization energy of
astatine in \(\mathrm{kJ} / \mathrm{mol} .\) (c) Comment on whether or not the
following first ionization energies support your answer to part (a):
\(\mathrm{Pb}, 715.6 \mathrm{~kJ} / \mathrm{mol} ; \mathrm{Bi}, 702.9
\mathrm{~kJ} / \mathrm{mol} ;\)
\(\mathrm{Po}, 811.8 \mathrm{~kJ} / \mathrm{mol} ; \mathrm{Rn}, 1037
\mathrm{~kJ} / \mathrm{mol}\)