Chapter 9: Problem 1
What is a Lewis dot symbol? To what elements does the symbol mainly apply?
Short Answer
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Chapter 9: Problem 1
What is a Lewis dot symbol? To what elements does the symbol mainly apply?
These are the key concepts you need to understand to accurately answer the question.
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Get started for freeDraw a Lewis structure for nitrogen pentoxide \(\left(\mathrm{N}_{2} \mathrm{O}_{5}\right)\) in which each \(\mathrm{N}\) is bonded to three \(\mathrm{O}\) atoms.
Most organic acids can be represented as \(\mathrm{RCOOH}\) where \(\mathrm{COOH}\) is the carboxyl group and \(\mathrm{R}\) is the rest of the molecule. (For example, \(\mathrm{R}\) is \(\mathrm{CH}_{3}\) in acetic acid, \(\mathrm{CH}_{3} \mathrm{COOH} .\) ) (a) Draw a Lewis structure for the carboxyl group. (b) Upon ionization, the carboxyl group is converted to the carboxylate group, \(\mathrm{COO}^{-}\). Draw resonance structures for the carboxylate group.
The formulas for the fluorides of the third-period elements are \(\mathrm{NaF}, \mathrm{MgF}_{2}, \mathrm{AlF}_{3}, \mathrm{SiF}_{4}, \mathrm{PF}_{5}, \mathrm{SF}_{6}\) and \(\mathrm{ClF}_{3}\). Classify these compounds as covalent or ionic.
From the lattice energy of \(\mathrm{KCl}\) in Table 9.1 and the ionization energy of \(\mathrm{K}\) and electron affinity of \(\mathrm{Cl}\) in Tables 8.2 and 8.3 , calculate the \(\Delta H^{\circ}\) for the reaction $$ \mathrm{K}(g)+\mathrm{Cl}(g) \longrightarrow \mathrm{KCl}(s) $$ (a) Draw three resonance structures to represent the ion. (b) Given the following information $$ 2 \mathrm{H}+\mathrm{H}^{+} \longrightarrow \mathrm{H}_{3}^{+} \quad \Delta H^{\circ}=-849 \mathrm{~kJ} / \mathrm{mol} $$ and $$ \mathrm{H}_{2} \longrightarrow 2 \mathrm{H} \quad \Delta H^{\circ}=436.4 \mathrm{~kJ} / \mathrm{mol} $$ calculate \(\Delta H^{\circ}\) for the reaction $$ \mathrm{H}^{+}+\mathrm{H}_{2} \longrightarrow \mathrm{H}_{3}^{+} $$
Write Lewis structures for the following molecules: (a) ICl, (b) \(\mathrm{PH}_{3}\), (c) \(\mathrm{P}_{4}\) (each \(\mathrm{P}\) is bonded to three other \(\mathrm{P}\) atoms (d) \(\mathrm{H}_{2} \mathrm{~S}\), (e) \(\mathrm{N}_{2} \mathrm{H}_{4}\), (f) \(\mathrm{HClO}_{3}\), (g) \(\mathrm{COBr}_{2}\) (C is bonded to \(\mathrm{O}\) and \(\mathrm{Br}\) atoms).
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