Chapter 4: Problem 3

Why did Newland's law of octaves fail?

Short Answer

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Answer: Newland's law of octaves failed because it did not provide a consistent and reliable pattern for organizing elements, especially for elements beyond the first 20. Moreover, it struggled to accommodate the unique properties and placement of transition metals and inaccurately placed multiple elements with similar properties into the same box, leading to an inadequate portrayal of element relationships. These limitations left room for the development of more accurate models like Mendeleev's periodic table.

Step by step solution

What is Newland's law of octaves?

Newland's law of octaves was an early attempt at organizing the known elements into a logical system. In 1864, John Newlands proposed that when elements are arranged in order of increasing atomic weights, every eighth element shares properties with the first, just like how musical notes repeat in octaves. This relationship seemed to work well for some elements, particularly for the first 20 elements.

Limitation 1: Inconsistent Patterns

One reason Newland's law of octaves failed is because the pattern of similarities did not hold true for all elements past the first 20. The regular periodicity he observed was not consistent throughout the entire periodic table. As new elements were discovered, they didn't fit into the pattern, and his law couldn't accurately predict their properties or placement in the table.

Limitation 2: Transition Metals

Newland's law of octaves struggled to accommodate the transition metals, which have their own unique properties and don't fit neatly into the pattern he proposed. Transition metals, like iron, copper, and zinc, could not be accurately placed according to his law, and their properties did not line up with the octaves.

Limitation 3: Placing Multiple Elements in One Box

Another problem with Newland's law was his decision to place multiple elements with similar properties into the same box in his table. This method of organization resulted in an inaccurate portrayal of element relationships and was inadequate in categorizing and explaining element behavior. In conclusion, Newland's law of octaves failed because it didn't provide a consistent, reliable pattern for organizing elements, and it couldn't account for the unique properties of some groups of elements like transition metals. The limitations of Newland's law led to the development of other models to explain the relationship between the elements, such as Mendeleev's periodic table.

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Why did Newland's law of octaves fail?

Short Answer

Step by step solution

What is Newland's law of octaves?

Limitation 1: Inconsistent Patterns

Limitation 2: Transition Metals

Limitation 3: Placing Multiple Elements in One Box

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