(a) The strength of a covalent bond depends on which factor/factors? (b) Classify covalent bonds depending on the strength. Compare those bonds.

Short Answer

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Answer: The strength of a covalent bond depends on two primary factors: bond length and bond multiplicity. Shorter bond lengths and higher bond multiplicity result in stronger covalent bonds. Covalent bonds can be classified based on their strength into three types: single covalent bonds (weakest), double covalent bonds, and triple covalent bonds (strongest).

Step by step solution

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Part (a): Factors Affecting Covalent Bond Strength

The strength of a covalent bond depends on two primary factors: bond length and bond multiplicity. 1. Bond Length: The bond length is the distance between the nuclei of the two bonded atoms. In general, shorter bond lengths correspond to stronger covalent bonds. This is because shorter bonds allow for more effective overlap of atomic orbitals, leading to a stronger attractive force between the bonding electrons and the positively charged nuclei. 2. Bond Multiplicity: Bond multiplicity refers to the number of electron pairs shared between two bonded atoms. A single covalent bond shares one electron pair, a double bond shares two electron pairs, and a triple bond shares three electron pairs. As bond multiplicity increases, more electron pairs are shared between atoms, leading to stronger covalent bonds.
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Part (b): Classification of Covalent Bonds Based on Strength

Covalent bonds can be classified into three types, depending on their bond multiplicity and relative strength: 1. Single Covalent Bonds: These bonds involve sharing of one electron pair between two atoms (e.g., the bond between hydrogen and chlorine in HCl). Single covalent bonds are weaker than double or triple covalent bonds because there is less electron density shared between the bonded atoms. 2. Double Covalent Bonds: These bonds involve sharing of two electron pairs between two atoms (e.g., the bond between two oxygen atoms in O2). Double covalent bonds are stronger than single covalent bonds because there is more electron density shared between the bonded atoms, resulting in a stronger attractive force between the atoms. 3. Triple Covalent Bonds: These bonds involve sharing of three electron pairs between two atoms (e.g., the bond between two nitrogen atoms in N2). Triple covalent bonds are the strongest type of covalent bond, as there is the most electron density shared between the bonded atoms, leading to a very strong attractive force between the atoms. In summary, the strength of covalent bonds generally increases as bond multiplicity increases (i.e., single < double < triple), and bond strength also tends to increase as bond length decreases.

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