Sterling silver is a solid solution of silver and copper. If a piece of a sterling silver necklace has a mass of \(105.0 \mathrm{~g}\) and a volume of \(10.12 \mathrm{~mL}\), calculate the mass percent of copper in the piece of necklace. Assume that the volume of silver present plus the volume of copper present equals the total volume. Refer to Table \(1.5\). Mass percent of copper \(=\frac{\text { mass of copper }}{\text { total mass }} \times 100\)

Short Answer

Expert verified
The mass percent of copper in the sterling silver necklace is approximately \(25.369\%.\)

Step by step solution

01

Find the densities of silver and copper from the given table

Refer to Table 1.5 and look for the densities of silver and copper: Density of silver (Ag) = 10.5 g/mL Density of copper (Cu) = 8.92 g/mL
02

Calculate the mass of silver using its volume and density

Let x be the volume of silver in mL and (10.12 - x) be the volume of copper. Using the total volume equation provided in the problem: x + (10.12 - x) = 10.12 mL Thus, x is the volume of silver and 10.12 - x is the volume of copper. Now, we'll use the density formula to calculate the mass of silver: mass of silver = volume of silver × density of silver mass of silver = x × 10.5 g/mL
03

Calculate the mass of copper using its volume and density

Now, calculate the mass of copper: mass of copper = volume of copper × density of copper mass of copper = (10.12-x) × 8.92 g/mL
04

Calculate the total mass of the necklace piece

The total mass of the necklace piece is given in the problem as 105.0 g.
05

Write the equation for the total mass of the necklace piece

We have the total mass of the necklace piece equal to the sum of the masses of silver and copper: 105.0 g = mass of silver + mass of copper
06

Solve the equation for x

Substitute the expressions of mass of silver and mass of copper from step 2 and 3 in the equation obtained in step 5: 105.0 g = x × 10.5 g/mL + (10.12 - x) × 8.92 g/mL Now, solve this equation for x. x ≈ 7.134 mL
07

Calculate the mass of copper present in the necklace piece

Now that we have the value of x, calculate the mass of copper using the expression from step 3: mass of copper ≈ (10.12 - 7.134) × 8.92 g/mL mass of copper ≈ 26.637 g
08

Calculate the mass percent of copper

Using the mass percent formula provided in the problem, we can find the mass percent of copper: mass percent of copper = (mass of copper / total mass) × 100 mass percent of copper ≈ (26.637 g / 105.0 g) × 100 mass percent of copper ≈ 25.369% The mass percent of copper in the sterling silver necklace is approximately 25.369%.

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