Chapter 10: Problem 111
When a person has a severe fever, one therapy used to reduce the fever is an "alcohol rub." Explain how the evaporation of alcohol from a person's skin removes heat energy from the body.
Chapter 10: Problem 111
When a person has a severe fever, one therapy used to reduce the fever is an "alcohol rub." Explain how the evaporation of alcohol from a person's skin removes heat energy from the body.
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The unit cell of MgO is shown below. Does \(\mathrm{MgO}\) have a structure like that of \(\mathrm{NaCl}\) or \(\mathrm{ZnS} ?\) If the density of \(\mathrm{MgO}\) is \(3.58 \mathrm{~g} / \mathrm{cm}^{3}\), estimate the radius (in centimeters) of the \(\mathrm{O}^{2-}\) anions and the \(\mathrm{Mg}^{2+}\) cations.
Iodine, like most substances, exhibits only three phases: solid, liquid, and vapor. The triple point of iodine is at 90 torr and \(115^{\circ} \mathrm{C}\). Which of the following statements concerning liquid \(\mathrm{I}_{2}\) must be true? Explain your answer. a. \(\mathrm{I}_{2}(l)\) is more dense than \(\mathrm{I}_{2}(g)\). b. \(\mathrm{I}_{2}(l)\) cannot exist above \(115^{\circ} \mathrm{C}\). c. \(\mathrm{I}_{2}(l)\) cannot exist at 1 atmosphere pressure. d. \(\mathrm{I}_{2}(l)\) cannot have a vapor pressure greater than 90 torr. e. \(\mathrm{I}_{2}(l)\) cannot exist at a pressure of 10 torr.
The \(\mathrm{CsCl}\) structure is a simple cubic array of chloride ions with a cesium ion at the center of each cubic array (see Exercise 67 ). Given that the density of cesium chloride is \(3.97 \mathrm{~g} / \mathrm{cm}^{3}\), and assuming that the chloride and cesium ions touch along the body diagonal of the cubic unit cell, calculate the distance between the centers of adjacent \(\mathrm{Cs}^{+}\) and \(\mathrm{Cl}^{-}\) ions in the solid. Compare this value with the expected distance based on the sizes of the ions. The ionic radius of \(\mathrm{Cs}^{+}\) is \(169 \mathrm{pm}\), and the ionic radius of \(\mathrm{Cl}^{-}\) is \(181 \mathrm{pm}\).
A \(20.0-\mathrm{g}\) sample of ice at \(-10.0^{\circ} \mathrm{C}\) is mixed with \(100.0 \mathrm{~g}\) water at \(80.0^{\circ} \mathrm{C}\). Calculate the final temperature of the mixture assuming no heat loss to the surroundings. The heat capacities of \(\mathrm{H}_{2} \mathrm{O}(s)\) and \(\mathrm{H}_{2} \mathrm{O}(l)\) are \(2.03\) and \(4.18 \mathrm{~J} / \mathrm{g} \cdot{ }^{\circ} \mathrm{C}\), respectively, and the enthalpy of fusion for ice is \(6.02 \mathrm{~kJ} / \mathrm{mol}\).
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