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Chapter 10: Problem 18

Will a crystalline solid or an amorphous solid give a simpler X-ray diffraction pattern? Why?

Short Answer

Expert verified
A crystalline solid will give a simpler X-ray diffraction pattern compared to an amorphous solid. This is because the regular, repeating atomic arrangement in crystalline solids results in sharp, distinct peaks in the diffraction pattern, making it easier to analyze and determine the atomic structure. In contrast, the irregular atomic arrangement in amorphous solids leads to complex and diffuse patterns with broad peaks.

Step by step solution

01

Understanding the difference between crystalline and amorphous solids

Crystalline solids have a long-range ordered arrangement of their atoms in a three-dimensional pattern, which repeats periodically. This means that the individual atoms, ions, or molecules in a crystalline solid are arranged in a regular, repeating pattern. In contrast, amorphous solids lack long-range order and have an irregular arrangement of their atoms, ions, or molecules.
02

Understanding X-ray diffraction

X-ray diffraction is a technique used to study the atomic structure of materials, like solids. In this process, an X-ray beam is directed at the material, and then the scattered X-rays are collected and analyzed. The resulting diffraction pattern contains information about the atomic arrangements within the material, which can be used to determine the distance between the atoms and the overall structure of the material.
03

Analyzing the effect of atomic arrangements on X-ray diffraction patterns

Given that crystalline solids have a regular, repeating atomic arrangement, their X-ray diffraction patterns are characterized by sharp, distinct peaks. These peaks occur at specific angles and result from constructive interference of the X-rays scattering off the atoms in the crystal lattice. In contrast, amorphous solids have an irregular atomic arrangement, which results in X-ray diffraction patterns with broad, diffuse peaks due to the lack of long-range order and the presence of varying atomic distances and angles.
04

Determining which type of solid produces a simpler X-ray diffraction pattern

In the case of a crystalline solid, the sharp and distinct peaks in the X-ray diffraction pattern make it easier to analyze and determine the atomic structure. On the other hand, amorphous solids produce more complex and diffuse patterns due to their irregular atomic arrangements. Therefore, a crystalline solid will give a simpler X-ray diffraction pattern compared to an amorphous solid.

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