Chapter 10: Problem 51
A certain form of lead has a cubic closest packed structure with an edge length of \(492 \mathrm{pm} .\) Calculate the value of the atomic radius and the density of lead.
Chapter 10: Problem 51
A certain form of lead has a cubic closest packed structure with an edge length of \(492 \mathrm{pm} .\) Calculate the value of the atomic radius and the density of lead.
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Get started for freeA \(0.250-\mathrm{g}\) chunk of sodium metal is cautiously dropped into a mixture of \(50.0 \mathrm{~g}\) water and \(50.0 \mathrm{~g}\) ice, both at \(0{ }^{\circ} \mathrm{C}\). The reaction is \(2 \mathrm{Na}(s)+2 \mathrm{H}_{2} \mathrm{O}(l) \longrightarrow 2 \mathrm{NaOH}(a q)+\mathrm{H}_{2}(g) \quad \Delta H=-368 \mathrm{~kJ}\) Will the ice melt? Assuming the final mixture has a specific heat capacity of \(4.18 \mathrm{~J} / \mathrm{g} \cdot{ }^{\circ} \mathrm{C}\), calculate the final temperature. The enthalpy of fusion for ice is \(6.02 \mathrm{~kJ} / \mathrm{mol}\).
Rationalize the differences in physical properties in terms of intermolecular forces for the following organic compounds. Compare the first three substances with each other, compare the last three with each other, and then compare all six. Can you account for any anomalies? $$ \begin{array}{|lccc|} \hline & \text { bp }\left({ }^{\circ} \mathrm{C}\right) & \operatorname{mp}\left({ }^{\circ} \mathrm{C}\right) & \Delta H_{\text {vap }}(\mathbf{k J} / \text { mol }) \\ \hline \text { Benzene, } \mathrm{C}_{6} \mathrm{H}_{6} & 80 & 6 & 33.9 \\ \text { Naphthalene, } & & & \\ \mathrm{C}_{10} \mathrm{H}_{8} & 218 & 80 & 51.5 \\ \text { Carbon tetra- } & & & \\ \text { chloride } & 76 & -23 & 31.8 \\ \text { Acetone, } & & & \\ \mathrm{CH}_{3} \mathrm{COCH}_{3} & 56 & -95 & 31.8 \\ \text { Acetic acid, } & & & \\ \mathrm{CH}_{3} \mathrm{CO}_{2} \mathrm{H} & 118 & 17 & 39.7 \\ \text { Benzoic acid, } & & & \\ \mathrm{C}_{6} \mathrm{H}_{5} \mathrm{CO}_{2} \mathrm{H} & 249 & 122 & 68.2 \\\ \hline \end{array} $$
An aluminum antimonide solid-state laser emits light with a wavelength of \(730 . \mathrm{nm}\). Calculate the band gap in joules.
Water in an open beaker evaporates over time. As the water is evaporating, is the vapor pressure increasing, decreasing, or staying the same? Why?
Hydrogen peroxide \(\left(\mathrm{H}_{2} \mathrm{O}_{2}\right)\) is a syrupy liquid with a relatively low vapor pressure and a normal boiling point of \(152.2^{\circ} \mathrm{C}\). Rationalize the differences of these physical properties from those of water.
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