Chapter 14: Problem 13
What is meant by pH? True or false: A strong acid solution always has a lower pH than a weak acid solution. Explain.
Chapter 14: Problem 13
What is meant by pH? True or false: A strong acid solution always has a lower pH than a weak acid solution. Explain.
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Get started for freeA typical sample of vinegar has a pH of \(3.0\). Assuming that vinegar is only an aqueous solution of acetic acid \(\left(K_{\mathrm{a}}=1.8 \times 10^{-5}\right)\), calculate the concentration of acetic acid in vinegar.
Zinc hydroxide is an amphoteric substance. Write equations that describe \(\mathrm{Zn}(\mathrm{OH})_{2}\) acting as a Brønsted-Lowry base toward \(\mathrm{H}^{+}\) and as a Lewis acid toward \(\mathrm{OH}^{-}\).
A codeine-containing cough syrup lists codeine sulfate as a major ingredient instead of codeine. The Merck Index gives \(\mathrm{C}_{36} \mathrm{H}_{44} \mathrm{~N}_{2} \mathrm{O}_{10} \mathrm{~S}\) as the formula for codeine sulfate. Describe the composition of codeine sulfate. (See Exercise 143.) Why is codeine sulfate used instead of codeine?
Calculate the \(\mathrm{pH}\) of a \(0.200 \mathrm{M}\) solution of \(\mathrm{C}_{5} \mathrm{H}_{5} \mathrm{NHF}\). Hint: \(\mathrm{C}_{5} \mathrm{H}_{5} \mathrm{NHF}\) is a salt composed of \(\mathrm{C}_{5} \mathrm{H}_{5} \mathrm{NH}^{+}\) and \(\mathrm{F}^{-}\) ions. The prin- cipal equilibrium in this solution is the best acid reacting with the best base; the reaction for the principal equilibrium is \(\mathrm{C}_{5} \mathrm{H}_{5} \mathrm{NH}^{+}(a q)+\mathrm{F}^{-}(a q) \rightleftharpoons\) \(\mathrm{C}_{5} \mathrm{H}_{5} \mathrm{~N}(a q)+\mathrm{HF}(a q) \quad K=8.2 \times 10^{-3}\)
A certain acid, HA, has a vapor density of \(5.11 \mathrm{~g} / \mathrm{L}\) when in the gas phase at a temperature of \(25^{\circ} \mathrm{C}\) and a pressure of \(1.00 \mathrm{~atm}\). When \(1.50 \mathrm{~g}\) of this acid is dissolved in enough water to make \(100.0 \mathrm{~mL}\) of solution, the \(\mathrm{pH}\) is found to be \(1.80\). Calculate \(K_{\mathrm{a}}\) for the acid.
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