Chapter 16: Problem 59
Write equations for the stepwise formation of each of the following complex ions. a. \(\mathrm{Ni}(\mathrm{CN})_{4}^{2-}\) b. \(\mathrm{V}\left(\mathrm{C}_{2} \mathrm{O}_{4}\right)_{3}{ }^{3-}\)
Chapter 16: Problem 59
Write equations for the stepwise formation of each of the following complex ions. a. \(\mathrm{Ni}(\mathrm{CN})_{4}^{2-}\) b. \(\mathrm{V}\left(\mathrm{C}_{2} \mathrm{O}_{4}\right)_{3}{ }^{3-}\)
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Get started for freea. Calculate the molar solubility of AgBr in pure water. \(K_{\text {sp }}\) for \(\mathrm{AgBr}\) is \(5.0 \times 10^{-13}\) b. Calculate the molar solubility of AgBr in \(3.0 M \mathrm{NH}_{3}\). The overall formation constant for \(\mathrm{Ag}\left(\mathrm{NH}_{3}\right)_{2}^{+}\) is \(1.7 \times 10^{7}\), that is, \(\mathrm{Ag}^{+}(a q)+2 \mathrm{NH}_{3}(a q) \longrightarrow \mathrm{Ag}\left(\mathrm{NH}_{3}\right)_{2}^{+}(a q) \quad K=1.7 \times 10^{7}\) c. Compare the calculated solubilities from parts a and b. Explain any differences. d. What mass of AgBr will dissolve in \(250.0 \mathrm{~mL}\) of \(3.0 \mathrm{M} \mathrm{NH}_{3}\) ? e. What effect does adding \(\mathrm{HNO}_{3}\) have on the solubilities calculated in parts a and b?
For which salt in each of the following groups will the solubility depend on pH? a. \(\mathrm{AgF}, \mathrm{AgCl}, \mathrm{AgBr}\) c. \(\mathrm{Sr}\left(\mathrm{NO}_{3}\right)_{2}, \mathrm{Sr}\left(\mathrm{NO}_{2}\right)_{2}\) b. \(\mathrm{Pb}(\mathrm{OH})_{2}, \mathrm{PbCl}_{2}\) d. \(\mathrm{Ni}\left(\mathrm{NO}_{3}\right)_{2}, \mathrm{Ni}(\mathrm{CN})_{2}\)
Calculate the mass of manganese hydroxide present in \(1300 \mathrm{~mL}\) of a saturated manganese hydroxide solution. For \(\mathrm{Mn}(\mathrm{OH})_{2}, K_{\mathrm{sp}}=\) \(2.0 \times 10^{-13}\) 89\. On a hot day, a \(200.0-\mathrm{mL}\) sample of a saturated solution of \(\mathrm{PbI}_{2}\) was allowed to evaporate until dry. If \(240 \mathrm{mg}\) of solid \(\mathrm{PbI}_{2}\) was collected after evaporation was complete, calculate the \(K_{\mathrm{sp}}\) value for \(\mathrm{PbI}_{2}\) on this hot day.
The solubility of the ionic compound \(\mathrm{M}_{2} \mathrm{X}_{3}\), having a molar mass of \(288 \mathrm{~g} / \mathrm{mol}\), is \(3.60 \times 10^{-7} \mathrm{~g} / \mathrm{L}\). Calculate the \(K_{\mathrm{sp}}\) of the compound.
A solution contains \(2.0 \times 10^{-3} \mathrm{M} \mathrm{Ce}^{3+}\) and \(1.0 \times 10^{-2} \mathrm{M} \mathrm{IO}_{3}^{3-}\). Will \(\mathrm{Ce}\left(\mathrm{IO}_{3}\right)_{3}(s)\) precipitate? \(\left[K_{\text {sp }}\right.\) for \(\mathrm{Ce}\left(\mathrm{IO}_{3}\right)_{3}\) is \(\left.3.2 \times 10^{-10} .\right]\)
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