Chapter 17: Problem 13
Entropy has been described as "time's arrow." Interpret this view of entropy.
Chapter 17: Problem 13
Entropy has been described as "time's arrow." Interpret this view of entropy.
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Get started for freeConsider the reaction $$\mathrm{H}_{2}(g)+\mathrm{Br}_{2}(g) \rightleftharpoons 2 \mathrm{HBr}(g)$$ where \(\Delta H^{\circ}=-103.8 \mathrm{~kJ} / \mathrm{mol} .\) In a particular experiment, equal moles of \(\mathrm{H}_{2}(\mathrm{~g})\) at \(1.00 \mathrm{~atm}\) and \(\mathrm{Br}_{2}(\mathrm{~g})\) at \(1.00 \mathrm{~atm}\) were mixed in a \(1.00\) -L flask at \(25^{\circ} \mathrm{C}\) and allowed to reach equilibrium. Then the molecules of \(\mathrm{H}_{2}\) at equilibrium were counted using a very sensitive technique, and \(1.10 \times 10^{13}\) molecules were found. For this reaction, calculate the values of \(K, \Delta G^{\circ}\), and \(\Delta S^{\circ}\).
The enthalpy of vaporization of chloroform \(\left(\mathrm{CHCl}_{3}\right)\) is \(31.4\) \(\mathrm{kJ} / \mathrm{mol}\) at its boiling point \(\left(61.7^{\circ} \mathrm{C}\right) .\) Determine \(\Delta S_{\mathrm{sys}}, \Delta S_{\mathrm{sur}}\), and \(\Delta S_{\text {univ }}\) when \(1.00 \mathrm{~mol}\) chloroform is vaporized at \(61.7^{\circ} \mathrm{C}\) and \(1.00 \mathrm{~atm} .\)
For the process \(\mathrm{A}(l) \longrightarrow \mathrm{A}(g)\), which direction is favored by changes in energy probability? Positional probability? Explain your answers. If you wanted to favor the process as written, would you raise or lower the temperature of the system? Explain.
For mercury, the enthalpy of vaporization is \(58.51 \mathrm{~kJ} / \mathrm{mol}\) and the entropy of vaporization is \(92.92 \mathrm{~J} / \mathrm{K} \cdot \mathrm{mol}\). What is the normal boiling point of mercury?
Consider the following system at equilibrium at \(25^{\circ} \mathrm{C}\) : $$\mathrm{PCl}_{3}(g)+\mathrm{Cl}_{2}(g) \rightleftharpoons \mathrm{PCl}_{5}(g) \quad \Delta G^{\circ}=-92.50 \mathrm{~kJ}$$ What will happen to the ratio of partial pressure of \(\mathrm{PCl}_{5}\) to partial pressure of \(\mathrm{PCl}_{3}\) if the temperature is raised? Explain completely.
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