Chapter 18: Problem 20
When balancing reactions in Chapter 3 , we did not mention that reactions must be charge balanced as well as mass balanced. What do charge balanced and mass balanced mean? How are redox reactions charge balanced?
Chapter 18: Problem 20
When balancing reactions in Chapter 3 , we did not mention that reactions must be charge balanced as well as mass balanced. What do charge balanced and mass balanced mean? How are redox reactions charge balanced?
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Get started for freeIt took \(150 . \mathrm{s}\) for a current of \(1.25 \mathrm{~A}\) to plate out \(0.109 \mathrm{~g}\) of \(\mathrm{a}\) metal from a solution containing its cations. Show that it is not possible for the cations to have a charge of \(1+\).
What reaction will take place at the cathode and the anode when each of the following is electrolyzed? a. molten \(\mathrm{KF}\) b. molten \(\mathrm{CuCl}_{2}\) c. molten \(\mathrm{MgI}_{2}\)
Electrolysis of an alkaline earth metal chloride using a current of \(5.00 \mathrm{~A}\) for \(748 \mathrm{~s}\) deposits \(0.471 \mathrm{~g}\) of metal at the cathode. What is the identity of the alkaline earth metal chloride?
An electrochemical cell consists of a nickel metal electrode immersed in a solution with \(\left[\mathrm{Ni}^{2+}\right]=1.0 M\) separated by a porous disk from an aluminum metal electrode. a. What is the potential of this cell at \(25^{\circ} \mathrm{C}\) if the aluminum electrode is placed in a solution in which \(\left[\mathrm{Al}^{3+}\right]=7.2 \times 10^{-3} M ?\) b. When the aluminum electrode is placed in a certain solution in which \(\left[\mathrm{Al}^{3+}\right]\) is unknown, the measured cell potential at \(25^{\circ} \mathrm{C}\) is \(1.62 \mathrm{~V} .\) Calculate \(\left[\mathrm{Al}^{3+}\right]\) in the unknown solution. (Assume Al is oxidized.)
In 1973 the wreckage of the Civil War ironclad USS Monitor was discovered near Cape Hatteras, North Carolina. [The Monitor and the CSS Virginia (formerly the USS Merrimack) fought the first battle between iron-armored ships.] In 1987 investigations were begun to see if the ship could be salvaged. It was reported in Time (June 22,1987 ) that scientists were considering adding sacrificial anodes of zinc to the rapidly corroding metal hull of the Monitor. Describe how attaching zinc to the hull would protect the Monitor from further corrosion.
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