Chapter 20: Problem 8
What is nitrogen fixation? Give some examples of nitrogen fixation.
Chapter 20: Problem 8
What is nitrogen fixation? Give some examples of nitrogen fixation.
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Get started for freeHow can the paramagnetism of \(\mathrm{O}_{2}\) be explained using the molecular orbital model?
Photogray lenses contain small embedded crystals of solid silver chloride. Silver chloride is light-sensitive because of the reaction $$\mathrm{AgCl}(s) \stackrel{\mathrm{hv}}{\longrightarrow} \mathrm{Ag}(s)+\mathrm{Cl}$$ Small particles of metallic silver cause the lenses to darken. In the lenses this process is reversible. When the light is removed, the reverse reaction occurs. However, when pure white silver chloride is exposed to sunlight it darkens; the reverse reaction does not occur in the dark. a. How do you explain this difference? b. Photogray lenses do become permanently dark in time. How do you account for this?
What is a disproportionation reaction? Use the following reduction potentials $$ \begin{aligned} \mathrm{ClO}_{3}^{-} &+3 \mathrm{H}^{+}+2 \mathrm{e}^{-} \longrightarrow \mathrm{HClO}_{2}+\mathrm{H}_{2} \mathrm{O} & & \mathscr{E}^{\circ}=1.21 \mathrm{~V} \\ \mathrm{HClO}_{2}+2 \mathrm{H}^{+}+2 \mathrm{e}^{-} \longrightarrow \mathrm{HClO}+\mathrm{H}_{2} \mathrm{O} & & \mathscr{E}^{\circ}=1.65 \mathrm{~V} \end{aligned} $$ to predict whether \(\mathrm{HClO}_{2}\) will disproportionate.
Arsenic reacts with oxygen to form oxides that react with water in a manner analogous to that of the phosphorus oxides. Write balanced chemical equations describing the reaction of arsenic with oxygen and the reaction of the resulting oxide with water.
In most compounds, the solid phase is denser than the liquid phase. Why isn't this true for water?
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