Chapter 22: Problem 30
Cumene is the starting material for the industrial production of acetone and phenol. The structure of cumene is Give the systematic name for cumene.
Chapter 22: Problem 30
Cumene is the starting material for the industrial production of acetone and phenol. The structure of cumene is Give the systematic name for cumene.
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Get started for freePolycarbonates are a class of thermoplastic polymers that are used in the plastic lenses of eyeglasses and in the shells of bicycle helmets. A polycarbonate is made from the reaction of bisphenol A (BPA) with phosgene \(\left(\mathrm{COCl}_{2}\right)\) : polycarbonate \(+2 n \mathrm{HCl}\) Phenol \(\left(\mathrm{C}_{6} \mathrm{H}_{5} \mathrm{OH}\right)\) is used to terminate the polymer (stop its growth). a. Draw the structure of the polycarbonate chain formed from the above reaction. b. Is this reaction a condensation or an addition polymerization?
Draw all the structural and geometrical (cis-trans) isomers of \(\mathrm{C}_{3} \mathrm{H}_{5} \mathrm{Cl} .\)
What is wrong with the following names? Give the correct name for each compound. a. 2 -ethylpropane b. 5 -iodo \(-5,6\) -dimethylhexane c. cis-4-methyl-3-pentene d. 2 -bromo- 3 -butanol
Three different organic compounds have the formula \(\mathrm{C}_{3} \mathrm{H}_{8} \mathrm{O}\). Only two of these isomers react with \(\mathrm{KMnO}_{4}\) (a strong oxidizing agent). What are the names of the products when these isomers react with excess \(\mathrm{KMnO}_{4}\) ?
Over 100 different kinds of mutant hemoglobin molecules have been detected in humans. Unlike sickle cell anemia (see Exercise 93), not all of these mutations are as serious. In one nonlethal mutation, glutamine substitutes for a single glutamic acid in normal hemoglobin. Rationalize why this substitution is nonlethal.
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