Chapter 22: Problem 70
Complete the following reactions. a. \(\mathrm{CH}_{3} \mathrm{CO}_{2} \mathrm{H}+\mathrm{CH}_{3} \mathrm{OH} \rightarrow\) b. \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{OH}+\mathrm{HCOOH} \rightarrow\)
Chapter 22: Problem 70
Complete the following reactions. a. \(\mathrm{CH}_{3} \mathrm{CO}_{2} \mathrm{H}+\mathrm{CH}_{3} \mathrm{OH} \rightarrow\) b. \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{OH}+\mathrm{HCOOH} \rightarrow\)
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Get started for freeCis-trans isomerism is also possible in molecules with rings. Draw the cis and trans isomers of 1,2 -dimethylcyclohexane. In Exercise 41, you drew all of the noncyclic structural and geometric isomers of \(\mathrm{C}_{4} \mathrm{H}_{7} \mathrm{~F}\). Now draw the cyclic structural and geometric isomers of \(\mathrm{C}_{4} \mathrm{H}_{7} \mathrm{~F}\).
Draw the structures of the two dipeptides that can be formed from serine and alanine.
Draw the structural formula for each of the following. a. formaldehyde (methanal) b. 4 -heptanone c. 3 -chlorobutanal d. 5,5 -dimethyl-2-hexanone
If you had a group of hydrocarbons, what structural features would you look at to rank the hydrocarbons in order of increasing boiling point?
Polychlorinated dibenzo- \(p\) -dioxins (PCDDs) are highly toxic substances that are present in trace amounts as by-products of some chemical manufacturing processes. They have been implicated in a number of environmental incidents- for example, the chemical contamination at Love Canal and the herbicide spraying The most toxic \(\mathrm{PCDD}\) is \(2,3,7,8\) -tetrachloro-dibenzo- \(p\) -dioxin. Draw the structure of this compound. Also draw the structures of two other isomers containing four chlorine atoms.
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