Chapter 22: Problem 96
Indicate the chiral carbon atoms found in the monosaccharides D-ribose and D-mannose.
Chapter 22: Problem 96
Indicate the chiral carbon atoms found in the monosaccharides D-ribose and D-mannose.
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Get started for freePolycarbonates are a class of thermoplastic polymers that are used in the plastic lenses of eyeglasses and in the shells of bicycle helmets. A polycarbonate is made from the reaction of bisphenol A (BPA) with phosgene \(\left(\mathrm{COCl}_{2}\right)\) : polycarbonate \(+2 n \mathrm{HCl}\) Phenol \(\left(\mathrm{C}_{6} \mathrm{H}_{5} \mathrm{OH}\right)\) is used to terminate the polymer (stop its growth). a. Draw the structure of the polycarbonate chain formed from the above reaction. b. Is this reaction a condensation or an addition polymerization?
Cumene is the starting material for the industrial production of acetone and phenol. The structure of cumene is Give the systematic name for cumene.
There are three isomers of dichlorobenzene, one of which has now replaced naphthalene as the main constituent of mothballs. a. Identify the ortho, the meta, and the para isomers of dichlorobenzene. b. Predict the number of isomers for trichlorobenzene. c. It turns out that the presence of one chlorine atom on a benzene ring will cause the next substituent to add ortho or para to the first chlorine atom on the benzene ring. What does this tell you about the synthesis of \(m\) -dichlorobenzene? d. Which of the isomers of trichlorobenzene will be the hardest to prepare?
ABS plastic is a tough, hard plastic used in applications requiring shock resistance. The polymer consists of three monomer units: acrylonitrile \(\left(\mathrm{C}_{3} \mathrm{H}_{3} \mathrm{~N}\right)\), butadiene \(\left(\mathrm{C}_{4} \mathrm{H}_{6}\right)\), and styrene \(\left(\mathrm{C}_{8} \mathrm{H}_{8}\right)\). a. Draw two repeating units of \(\mathrm{ABS}\) plastic assuming that the three monomer units react in a \(1: 1: 1\) mole ratio and react in the same order as the monomers listed above. b. A sample of ABS plastic contains \(8.80 \% \mathrm{~N}\) by mass. It took \(0.605 \mathrm{~g} \mathrm{Br}_{2}\) to react completely with a \(1.20-\mathrm{g}\) sample of \(\mathrm{ABS}\) plastic. What is the percent by mass of acrylonitrile, butadiene, and styrene in this polymer sample? c. ABS plastic does not react in a \(1: 1: 1\) mole ratio among the three monomer units. Using the results from part b, determine the relative numbers of the monomer units in this sample of ABS plastic.
Name all the alcohols that have the formula \(\mathrm{C}_{5} \mathrm{H}_{12} \mathrm{O}\). How many ethers have the formula \(\mathrm{C}_{5} \mathrm{H}_{12} \mathrm{O}\) ?
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