A \(2.077-g\) sample of an element, which has an atomic mass between 40 and 55 , reacts with oxygen to form \(3.708 \mathrm{~g}\) of an oxide. Determine the formula of the oxide (and identify the element).

Short Answer

Expert verified
The empirical formula of the oxide is \(MnO\) and the element is Manganese.

Step by step solution

01

Calculate the mass of oxygen in the oxide

In order to find the empirical formula of the oxide, we must first calculate the mass of oxygen in the compound. This can be done by subtracting the mass of the element from the mass of the oxide: Mass of Oxygen = Mass of Oxide - Mass of Element Mass of Oxygen = \(3.708 g - 2.077 g = 1.631 g\) Now we have the mass of the element (2.077 g) and the mass of oxygen (1.631 g) in the oxide.
02

Convert the mass of the element and oxygen into moles

Next, we will convert the mass of the element and oxygen into moles using their respective molar masses. The molar mass of oxygen is 16.00 g/mol. Moles of Element = Mass of Element / Molar Mass of Element (unknown) Moles of Oxygen = Mass of Oxygen / Molar Mass of Oxygen Moles of Oxygen = \(1.631 g \div 16.00 g/mol = 0.102 mol\) Since we don't know the molar mass of the element, we will define it as \(x\). Moles of Element = \(2.077 g \div x g/mol\)
03

Determine the mole ratio of the element to oxygen in the oxide

In order to find the empirical formula, we need to determine the mole ratio of the element to oxygen in the oxide. To do this, we will divide the moles of the element and oxygen by the smaller number. Mole Ratio(Element : Oxygen) = \(\frac{2.077 g \div (x g/mol)}{0.102 mol}\) Since we are trying to find an integer ratio, we can simplify the expression by multiplying both sides by \(x\): Mole Ratio (Element : Oxygen) = \(\frac{2.077 g}{0.102 mol} \cdot x\)
04

Find the empirical formula of the oxide

Now, we need to find the empirical formula of the oxide by finding the values of \(x\) that result in an integer ratio of the element to oxygen. Since the atomic mass of the element is given to be between 40 and 55, we can try different values of \(x\) within this range to find the integer ratio. We can try \(x = 40\): Mole Ratio (Element : Oxygen) = \(\frac{2.077 g}{0.102 mol} \cdot 40 \approx 0.81\) This ratio is not close to an integer value. Let's try \(x = 55\): Mole Ratio (Element : Oxygen) = \(\frac{2.077 g}{0.102 mol} \cdot 55 \approx 1.12\) This ratio is close to the integer value 1. Therefore, the empirical formula is \(EO\), where E is the unknown element.
05

Identify the element by finding its atomic mass

Since we found that the empirical formula is close to \(EO\) when \(x = 55\), the atomic mass of the element should be approximately 55. Checking the periodic table, we can see that the element with an atomic mass closest to 55 is Manganese (Mn). So, the empirical formula of the oxide is \(MnO\), and the element is Manganese.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Stoichiometry
Stoichiometry is like a roadmap for chemistry, crucial in the world of chemistry for predicting how much product one can produce from a given amount of reactants. It's based on the conservation of mass, where the total mass of reactants equals the total mass of products in a chemical reaction.

One key to mastering stoichiometry is to understand the mole concept, which allows chemists to count particles by weighing them. But how does this relate to empirical formula calculations? When you're given the mass of a compound and its constituent elements – like in our exercise – stoichiometry enables you to determine the simplest whole number ratio of atoms within that compound, essentially decoding its formula.

Here's a quick rundown based on our problem: After finding the mass of oxygen in the oxide (1.631 g), we employ stoichiometry to convert this mass into moles, a step that paves the way to uncovering the mole ratio between the element and oxygen. A common stumbling block at this point is forgetting to compare the ratios to identify the empirical formula, a simple proportional relationship that stoichiometry simplifies for us.
Mole Concept
The mole concept is every chemist's best friend when it comes to understanding the world on a microscopic level. It's essentially a counting unit, like a dozen or a gross, but for atoms and molecules. One mole is Avogadro's number of particles, which is approximately 6.022 x 1023.

Why is this so handy? Well, atoms and molecules are too small to count individually, but we can weigh them and use their molar masses to convert to moles. For example, as shown in the step by step solution, to find the moles of oxygen we divided its mass by its molar mass. The concept really shines when you're trying to find the ratio of atoms – because a mole of any element has the same number of atoms, it lets you directly compare ratios by moles, not by mass. That's exactly what we did to determine the formula of the oxide in the given problem.

Remember, for more accuracy in empirical formula calculations, be precise with molar masses and consider using a mole-to-mole conversion factor based on the balanced chemical equation when applicable.
Molar Mass
Molar mass is the bridge that connects the microscale world of atoms to the macroscale world we can measure. It's defined as the mass of one mole of a substance (expressed in grams per mole, g/mol), and this varies for each element due to differences in atomic structure and mass.

In the exercise, we used the molar mass of oxygen (16.00 g/mol) to convert the mass of oxygen to moles. If you're anticipating finding an empirical formula, knowing correct molar masses and using them accurately is vital. For instance, the molar mass of the unknown element was the x variable we were solving for, which required trial and error within a given range to discover the integer ratio and identify the element as Manganese.

Tip for improvement: Always double-check that you're using accurate molar masses, which can be found on the periodic table or a chemical database. This ensures you don't introduce errors into your mole calculations, which could ripple through to your empirical formula result.

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Most popular questions from this chapter

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