Chapter 5: Problem 51
A 2.50-L container is filled with \(175 \mathrm{~g}\) argon. a. If the pressure is \(10.0\) atm, what is the temperature? b. If the temperature is \(225 \mathrm{~K}\), what is the pressure?
Chapter 5: Problem 51
A 2.50-L container is filled with \(175 \mathrm{~g}\) argon. a. If the pressure is \(10.0\) atm, what is the temperature? b. If the temperature is \(225 \mathrm{~K}\), what is the pressure?
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Get started for freeMethanol \(\left(\mathrm{CH}_{3} \mathrm{OH}\right)\) can be produced by the following reaction: $$ \mathrm{CO}(g)+2 \mathrm{H}_{2}(g) \longrightarrow \mathrm{CH}_{3} \mathrm{OH}(g) $$ Hydrogen at STP flows into a reactor at a rate of \(16.0 \mathrm{~L} / \mathrm{min}\) Carbon monoxide at STP flows into the reactor at a rate of \(25.0\) L/min. If \(5.30 \mathrm{~g}\) methanol is produced per minute, what is the percent yield of the reaction?
At elevated temperatures, sodium chlorate decomposes to produce sodium chloride and oxygen gas. A \(0.8765-g\) sample of impure sodium chlorate was heated until the production of oxygen gas ceased. The oxygen gas collected over water occupied \(57.2\) \(\mathrm{mL}\) at a temperature of \(22^{\circ} \mathrm{C}\) and a pressure of 734 torr. Calculate the mass percent of \(\mathrm{NaClO}_{3}\) in the original sample. (At \(22^{\circ} \mathrm{C}\) the vapor pressure of water is \(19.8\) torr.)
Consider three identical flasks filled with different gases. Flask A: \(\mathrm{CO}\) at 760 torr and \(0^{\circ} \mathrm{C}\) Flask B: \(\mathrm{N}_{2}\) at 250 torr and \(0^{\circ} \mathrm{C}\) Flask C: \(\mathrm{H}_{2}\) at 100 torr and \(0^{\circ} \mathrm{C}\) a. In which flask will the molecules have the greatest average kinetic energy? b. In which flask will the molecules have the greatest average velocity?
Metallic molybdenum can be produced from the mineral molybdenite, \(\mathrm{MoS}_{2}\). The mineral is first oxidized in air to molybdenum trioxide and sulfur dioxide. Molybdenum trioxide is then reduced to metallic molybdenum using hydrogen gas. The balanced equations are $$ \begin{aligned} \mathrm{MoS}_{2}(s)+\frac{2}{2} \mathrm{O}_{2}(g) & \longrightarrow \mathrm{MoO}_{3}(s)+2 \mathrm{SO}_{2}(g) \\ \mathrm{MoO}_{3}(s)+3 \mathrm{H}_{2}(g) & \longrightarrow \mathrm{Mo}(s)+3 \mathrm{H}_{2} \mathrm{O}(l) \end{aligned} $$ Calculate the volumes of air and hydrogen gas at \(17^{\circ} \mathrm{C}\) and \(1.00\) atm that are necessary to produce \(1.00 \times 10^{3} \mathrm{~kg}\) pure molybdenum from \(\mathrm{MoS}_{2}\). Assume air contains \(21 \%\) oxygen by volume and assume \(100 \%\) yield for each reaction.
Methane \(\left(\mathrm{CH}_{4}\right)\) gas flows into a combustion chamber at a rate of 200\. \(\mathrm{L} / \mathrm{min}\) at \(1.50 \mathrm{~atm}\) and ambient temperature. Air is added to the chamber at \(1.00 \mathrm{~atm}\) and the same temperature, and the gases are ignited. a. To ensure complete combustion of \(\mathrm{CH}_{4}\) to \(\mathrm{CO}_{2}(\mathrm{~g})\) and \(\mathrm{H}_{2} \mathrm{O}(g)\), three times as much oxygen as is necessary is reacted. Assuming air is 21 mole percent \(\mathrm{O}_{2}\) and 79 mole percent \(\mathrm{N}_{2}\), calculate the flow rate of air necessary to deliver the required amount of oxygen. b. Under the conditions in part a, combustion of methane was not complete as a mixture of \(\mathrm{CO}_{2}(g)\) and \(\mathrm{CO}(g)\) was produced. It was determined that \(95.0 \%\) of the carbon in the exhaust gas was present in \(\mathrm{CO}_{2}\). The remainder was present as carbon in CO. Calculate the composition of the exhaust gas in terms of mole fraction of \(\mathrm{CO}, \mathrm{CO}_{2}, \mathrm{O}_{2}, \mathrm{~N}_{2}\), and \(\mathrm{H}_{2} \mathrm{O} .\) Assume \(\mathrm{CH}_{4}\) is completely reacted and \(\mathrm{N}_{2}\) is unreacted.
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