Chapter 5: Problem 64
A student adds \(4.00 \mathrm{~g}\) dry ice (solid \(\mathrm{CO}_{2}\) ) to an empty balloon. What will be the volume of the balloon at STP after all the dry jce sublimes (converts to gaseous \(\mathrm{CO}_{2}\) )?
Short Answer
Expert verified
The volume of the balloon will be approximately 2.42 L after all the dry ice sublimes at STP.
Step by step solution
01
Find the number of moles of dry ice
First, use the molar mass of CO2 to convert the mass of dry ice into moles. The molar mass of CO2 is approximately 44.01 g/mol.
The number of moles of dry ice (n) can be calculated as follows:
n = (mass of CO2) / (molar mass of CO2)
n = \( \frac{4.00}{44.01} \) moles
02
Use the Ideal Gas Law and STP conditions
Next, we'll use the Ideal Gas Law (PV = nRT) along with the conditions of STP to find the volume of the baloon.
- The gas constant (R) = 0.0821 L atm/(mol K)
- For STP, the temperature (T) = 273.15 K
- Pressure (P) = 1 atm
03
Substitute given values and solve for Volume(V)
Substitute the given values of n, R, T, and P into the Ideal Gas Law formula:
(1 atm) * V = (4.00/44.01 moles) * (0.0821 L atm/(mol K)) * (273.15 K)
Simplify the equation by dividing both sides by 1 atm and multiplying the constants together:
V = \( \frac{4.00}{44.01} \) moles * (0.0821 L atm/(mol K)) * (273.15 K)
04
Calculate the volume of the balloon
Calculate the final volume of the balloon:
V = (4.00/44.01) * 0.0821 * 273.15
V ≈ 2.42 L
The volume of the balloon will be approximately 2.42 L after all the dry ice sublimes at STP.
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Molar Mass
Understanding the molar mass of a compound is a fundamental concept in chemistry. The molar mass, often measured in grams per mole (g/mol), is the weight of one mole of a substance. One mole of any substance contains Avogadro's number of entities (\(6.02 \times 10^{23}\) atoms, molecules, or ions).
For example, carbon dioxide (\(CO_2\)) has a molar mass of approximately 44.01 g/mol; this is calculated by summing up the molar masses of one carbon atom (approximately 12.01 g/mol) and two oxygen atoms (approximately 16.00 g/mol each).
In practical terms, if you have 44.01 grams of \(CO_2\), this quantity is equivalent to 1 mole of \(CO_2\) molecules. Knowing the molar mass allows you to convert between the mass of a substance and the number of moles, enabling stoichiometric calculations in chemical reactions and gas law problems.
For example, carbon dioxide (\(CO_2\)) has a molar mass of approximately 44.01 g/mol; this is calculated by summing up the molar masses of one carbon atom (approximately 12.01 g/mol) and two oxygen atoms (approximately 16.00 g/mol each).
In practical terms, if you have 44.01 grams of \(CO_2\), this quantity is equivalent to 1 mole of \(CO_2\) molecules. Knowing the molar mass allows you to convert between the mass of a substance and the number of moles, enabling stoichiometric calculations in chemical reactions and gas law problems.
STP (Standard Temperature and Pressure)
The concept of Standard Temperature and Pressure (STP) is used to provide a common reference for gas measurements and calculations. At STP, the temperature is set to 0°C (273.15 K) and the pressure to 1 atmosphere (atm).
STP conditions are crucial when working with gases because they allow chemists to compare the behavior of different gases under the same standard conditions. For instance, under STP, one mole of any ideal gas occupies 22.41 liters. This standard volume can be used to predict how changes in temperature and pressure will affect a gas. The use of STP conditions also simplifies calculations, as they provide a consistent set of values for temperature and pressure that can be used in equations such as the Ideal Gas Law.
STP conditions are crucial when working with gases because they allow chemists to compare the behavior of different gases under the same standard conditions. For instance, under STP, one mole of any ideal gas occupies 22.41 liters. This standard volume can be used to predict how changes in temperature and pressure will affect a gas. The use of STP conditions also simplifies calculations, as they provide a consistent set of values for temperature and pressure that can be used in equations such as the Ideal Gas Law.
Gas Constant (R)
The Gas Constant (R) is a fundamental constant in the Ideal Gas Law equation: \(PV=nRT\). It relates pressure (P), volume (V), number of moles (n), and temperature (T) for an ideal gas. The value of R depends on the units used for pressure, volume, and temperature but is commonly expressed as 0.0821 L atm/(mol K) for calculations involving liters, atmospheres, and Kelvin.
The gas constant provides a link between the macroscopic properties of gases and their molecular quantities, bridging the gap between the microscopic world of molecules and the observable behavior of gas samples in the lab. When using the Ideal Gas Law, it's essential to ensure that the units are consistent and match those of the gas constant being used.
The gas constant provides a link between the macroscopic properties of gases and their molecular quantities, bridging the gap between the microscopic world of molecules and the observable behavior of gas samples in the lab. When using the Ideal Gas Law, it's essential to ensure that the units are consistent and match those of the gas constant being used.
Mole Conversion
Mole conversion is a critical skill in chemistry, allowing scientists to relate the mass of a substance to the number of particles it contains. Given the molar mass of a compound (g/mol), you can calculate the number of moles from the substance's mass by dividing the mass by the molar mass.
For instance, in our original exercise, we converted the mass of dry ice (solid \(CO_2\)) into moles by dividing by its molar mass. Such conversions are essential for predicting reactant consumption, product formation in chemical reactions, and analyzing gas volumes using the Ideal Gas Law.
Additionally, mole conversions are not limited to masses and volumes; they can extend to represent concentrations (in molarity) and also to relate the number of moles to Avogadro's number for counting individual atoms or molecules in a given sample.
For instance, in our original exercise, we converted the mass of dry ice (solid \(CO_2\)) into moles by dividing by its molar mass. Such conversions are essential for predicting reactant consumption, product formation in chemical reactions, and analyzing gas volumes using the Ideal Gas Law.
Additionally, mole conversions are not limited to masses and volumes; they can extend to represent concentrations (in molarity) and also to relate the number of moles to Avogadro's number for counting individual atoms or molecules in a given sample.