Chapter 5: Problem 95
Calculate the average kinetic energies of \(\mathrm{CH}_{4}(g)\) and \(\mathrm{N}_{2}(g)\) molecules at \(273 \mathrm{~K}\) and \(546 \mathrm{~K}\).
Chapter 5: Problem 95
Calculate the average kinetic energies of \(\mathrm{CH}_{4}(g)\) and \(\mathrm{N}_{2}(g)\) molecules at \(273 \mathrm{~K}\) and \(546 \mathrm{~K}\).
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Get started for freeConsider two different containers, each filled with 2 moles of \(\mathrm{Ne}(\mathrm{g}) .\) One of the containers is rigid and has constant volume. The other container is flexible (like a balloon) and is capable of changing its volume to keep the external pressure and internal pressure equal to each other. If you raise the temperature in both containers, what happens to the pressure and density of the gas inside each container? Assume a constant external pressure.
Methane \(\left(\mathrm{CH}_{4}\right)\) gas flows into a combustion chamber at a rate of 200\. \(\mathrm{L} / \mathrm{min}\) at \(1.50 \mathrm{~atm}\) and ambient temperature. Air is added to the chamber at \(1.00 \mathrm{~atm}\) and the same temperature, and the gases are ignited. a. To ensure complete combustion of \(\mathrm{CH}_{4}\) to \(\mathrm{CO}_{2}(\mathrm{~g})\) and \(\mathrm{H}_{2} \mathrm{O}(g)\), three times as much oxygen as is necessary is reacted. Assuming air is 21 mole percent \(\mathrm{O}_{2}\) and 79 mole percent \(\mathrm{N}_{2}\), calculate the flow rate of air necessary to deliver the required amount of oxygen. b. Under the conditions in part a, combustion of methane was not complete as a mixture of \(\mathrm{CO}_{2}(g)\) and \(\mathrm{CO}(g)\) was produced. It was determined that \(95.0 \%\) of the carbon in the exhaust gas was present in \(\mathrm{CO}_{2}\). The remainder was present as carbon in CO. Calculate the composition of the exhaust gas in terms of mole fraction of \(\mathrm{CO}, \mathrm{CO}_{2}, \mathrm{O}_{2}, \mathrm{~N}_{2}\), and \(\mathrm{H}_{2} \mathrm{O} .\) Assume \(\mathrm{CH}_{4}\) is completely reacted and \(\mathrm{N}_{2}\) is unreacted.
Small quantities of hydrogen gas can be prepared in the laboratory by the addition of aqueous hydrochloric acid to metallic zinc. $$ \mathrm{Zn}(s)+2 \mathrm{HCl}(a q) \longrightarrow \mathrm{ZnCl}_{2}(a q)+\mathrm{H}_{2}(g) $$ Typically, the hydrogen gas is bubbled through water for collection and becomes saturated with water vapor. Suppose \(240 . \mathrm{mL}\) of hydrogen gas is collected at \(30 .{ }^{\circ} \mathrm{C}\) and has a total pressure of \(1.032\) atm by this process. What is the partial pressure of hydrogen gas in the sample? How many grams of zinc must have reacted to produce this quantity of hydrogen? (The vapor pressure of water is 32 torr at \(30^{\circ} \mathrm{C}\).)
A bicycle tire is filled with air to a pressure of 75 . psi at a temperature of \(19^{\circ} \mathrm{C}\). Riding the bike on asphalt on a hot day increases the temperature of the tire to \(58^{\circ} \mathrm{C}\). The volume of the tire increases by \(4.0 \%\). What is the new pressure in the bicycle tire?
The average lung capacity of a human is \(6.0 \mathrm{~L}\). How many moles of air are in your lungs when you are in the following situations? a. At sea level \((T=298 \mathrm{~K}, P=1.00 \mathrm{~atm})\). b. \(10 . \mathrm{m}\) below water \((T=298 \mathrm{~K}, P=1.97 \mathrm{~atm})\). c. At the top of Mount Everest \((T=200 . \mathrm{K}, P=0.296 \mathrm{~atm})\).
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